Synergistic ligand effect for the construction of titanium-oxo clusters with planar chirality and high solution stability

Dalton Transactions : an International Journal of Inorganic Chemistry
Qing-Rong DingLei Zhang

Abstract

A synergistic effect between dimethylglyoxime (to stabilize the Ti-O ribbon) and nonlinear dicarboxylate ligands (to bend the Ti-O ribbon) has been developed to form a series of planar chiral titanium-oxo clusters with high solution stability. The charality of the obtained clusters has been studied by X-ray structural and CD spectroscopy analysis.

References

Apr 29, 2009·Journal of the American Chemical Society·Xiang-Jian KongZhiping Zheng
Jan 11, 2011·Chemical Society Reviews·Laurence Rozes, Clément Sanchez
Jun 19, 2013·Chemical Communications : Chem Comm·Hao WangXian-He Bu
Jan 23, 2014·Angewandte Chemie·Yaokang LvDominic S Wright
May 14, 2014·Chemical Reviews·Philip CoppensElżbieta Trzop
Oct 29, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jin-Le HouJie Dai
Feb 20, 2016·Journal of the American Chemical Society·Mei-Yan GaoJian Zhang
Aug 16, 2016·Journal of the American Chemical Society·Guanyun ZhangYifeng Wang
Jan 24, 2017·Chemical Communications : Chem Comm·Bai-Qiao SongZhong-Min Su
Nov 14, 2017·Chemistry : a European Journal·Michaela-Christina MelcherDaniel Strand
Nov 28, 2017·Chemical Society Reviews·Wei-Hui FangJian Zhang
Dec 8, 2017·Journal of the American Chemical Society·Guanyun ZhangYifeng Wang
Nov 30, 2018·Journal of the American Chemical Society·Weimin XuanLeroy Cronin
Jun 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Qing-Rong DingJian Zhang
Sep 29, 2019·Chemical Communications : Chem Comm·Pei-Yi LiuJie Dai

❮ Previous
Next ❯

Methods Mentioned

BETA
circular dichroism
X-ray

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.