Syntheses and Promising Properties of Dense Energetic 5,5'-Dinitramino-3,3'-azo-1,2,4-oxadiazole and Its Salts

Angewandte Chemie
Yongxing TangJean'ne M Shreeve

Abstract

A planar energetic molecule with high density, 5,5'-dinitramino-3,3'-azo-1,2,4-oxadiazole (4), was obtained by the nitration of 5,5'-diamino-3,3'-azo-1,2,4-oxadiazole using 100 % nitric acid. In addition, selected nitrogen-rich salts were prepared. Of them, the neutral compound 4 and its hydroxylammonium salt, 6, were further confirmed by single-crystal X-ray diffraction. Physicochemical and energetic properties including density, thermal stability, and sensitivity were investigated. The energetic performance from the calculated heats of formation and experimental densities indicates that many of them have potential applications as energetic materials.

References

Oct 13, 2005·Chemical Reviews·Zhongfang ChenPaul von Ragué Schleyer
Feb 24, 2006·Organic Letters·Hossein Fallah-Bagher-ShaidaeiPaul v R Schleyer
Jun 6, 2008·Journal of the American Chemical Society·Chaoyang ZhangHui Huang
Mar 30, 2010·Angewandte Chemie·Grégoire HervéHervé Graindorge
Aug 19, 2010·Journal of the American Chemical Society·Yu-Chuan LiSi-Ping Pang
Sep 28, 2010·Journal of Molecular Modeling·Vikas Dasharath GhuleSurya P Tewari
Nov 13, 2010·Journal of the American Chemical Society·Michael GöbelJörg Stierstorfer
Mar 10, 2011·Inorganic Chemistry·Thomas M Klapötke, Davin G Piercey
Aug 16, 2011·Chemical Reviews·Haixiang Gao, Jean'ne M Shreeve
Dec 14, 2011·Journal of Computational Chemistry·Tian Lu, Feiwu Chen
Jan 24, 2012·Chemistry : a European Journal·Zhanda FuFu-Xue Chen
Feb 23, 2013·BMJ Case Reports·Peter Ng
Jan 1, 2014·BMJ Case Reports·Suheil Artul
Apr 26, 2014·Chemistry : a European Journal·Ping YinJean'ne M Shreeve
May 9, 2014·Chemistry : a European Journal·Marcos A KettnerSwetlana Wunder
Jan 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·R HaigesK O Christe
Jun 23, 2015·Angewandte Chemie·Dennis FischerJörg Stierstorfer
Jul 3, 1996·Journal of the American Chemical Society·Paul von Ragué SchleyerNicolaas J R van Eikema Hommes

❮ Previous
Next ❯

Citations

Jul 1, 2017·Chemistry : a European Journal·Piao HeJianguo Zhang
Oct 12, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Qiong YuHongwei Yang
Nov 20, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhi-Bin ZhangJian-Guo Zhang
Sep 28, 2017·Chemistry : a European Journal·Yongxing TangJean'ne M Shreeve
Sep 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Hualin XiongGuangbin Cheng
Jun 4, 2021·Langmuir : the ACS Journal of Surfaces and Colloids·Jinhao ZhangRufang Peng

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

© 2021 Meta ULC. All rights reserved