Syntheses, crystal structures, and luminescent properties of novel layered lanthanide sulfonate-phosphonates

Inorganic Chemistry
Jun-Ling SongJiang-Gao Mao

Abstract

Hydrothermal reactions of lanthanide metal salts with MeN(CH(2)CO(2)H)(CH(2)PO(3)H(2)) (H(3)L) and 5-sulfoisophthalic acid monosodium salt (NaH(2)BTS) lead to four isomorphous lanthanide carboxylate-phosphonate-sulfonate hybrids, namely, Ln(H(2)L)(HBTS)(H(2)O)(2).H(2)O (Ln = La (1), Pr (2), Nd (3), Gd (4)). Their structures have been established by X-ray single-crystal diffraction. The interconnection of the lanthanide(III) ions by carboxylate-phosphonate ligands results in a 1D double chain; these double chains are further bridged by bidentate bridging carboxylate-sulfonate ligands to form a <011> layer. The luminescent properties of compounds 3 and 4 have also been studied.

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Citations

Nov 17, 2006·Chemical Communications : Chem Comm·Yan-Qiong SunGuo-Yu Yang
Jul 15, 2011·Acta Crystallographica. Section E, Structure Reports Online·Wei-Ping WuLi-Ke Zou
Aug 10, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Xin-Min GanRobert T Paine
Nov 4, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Ruibiao FuXintao Wu
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Jun 30, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Mei WangQiu-Tian Liu
Nov 3, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Pei-Xin LiJiang-Gao Mao
Jun 6, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Xun FengBei Ya Su
Jan 15, 2005·Chemistry : a European Journal·Jun-Ling Song, Jiang-Gao Mao
Nov 29, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiang-Ying QianJiang-Gao Mao
Apr 20, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Yan-Yu ZhuKai Chen
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Jan 30, 2008·Inorganic Chemistry·Bing-Ping YangJiang-Gao Mao
Jun 30, 2015·Chemical Reviews·Joydeb Goura, Vadapalli Chandrasekhar

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