Syntheses, spectroscopy, and crystal structures of 3-(4-bromo-phen-yl)-1,5-di-phenyl-formazan and the 3-(4-bromo-phen-yl)-1,5-di-phenyl-verdazyl radical and the crystal structure of the by-product 5-anilino-3-(4-bromo-phen-yl)-1-phenyl-1H -1,2,4-triazole

Acta Crystallographica. Section E, Crystallographic Communications
Gregor Schnakenburg, Andreas Meyer

Abstract

The title compounds, C19H15BrN4, C20H16BrN4 and C20H15BrN4, are nitro-gen-rich organic compounds that are related by their synthesis. The verdazyl radical, in which stacking leads to anti-ferromagnetic inter-actions, was reported previously [Iwase et al. (2013 ▸). Phys. Rev. B, 88, 184431]. For this compound, improved structural data and spectroscopic data are presented. The other two compounds have been crystallized for the first time and form stacks of dimers, roughly along the a-axis direction of the crystal. The formazan mol-ecule shows signs of rapid intra-molecular H-atom exchange typical for this class of compounds and spectroscopic data are provided in addition to the crystal structure. The triazole compound appears to be a side-product of the verdazyl synthesis.

References

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Methods Mentioned

BETA
column chromatography
X-ray

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