Synthesis and activation potential of an open shell diphosphine

Chemical Communications : Chem Comm
Kai HelmdachWolfram W Seidel

Abstract

A paramagnetic WIIIalkyne complex bearing free terminal diphenylphosphino groups at the side-on coordinated alkyne was synthesized using a stepwise template strategy. This moderately stable metal supported open shell diphosphine shows an unprecedented spontaneous splitting of nitric oxide providing a WII-η2-C2{P(NH2)Ph2}{P(O)Ph2}+complex featuring an amino phosphonium and a phosphine oxide substituent.

References

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Citations

Sep 27, 2018·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Vladimir V VoroninValentine P Ananikov
Jun 25, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Annie L ColebatchAnthony F Hill
Nov 7, 2019·Chemical Communications : Chem Comm·Brian J CookR Morris Bullock
Jun 27, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Kai HelmdachWolfram W Seidel
Mar 18, 2020·Chemistry : a European Journal·Helge LangeWolfram W Seidel
Apr 15, 2021·Inorganic Chemistry·Madeleine A EhweinerNadia C Mösch-Zanetti
Aug 17, 2021·Organometallics·Madeleine A EhweinerNadia C Mösch-Zanetti

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