Synthesis and Characterization of Free and Grafted N -Halamine Nanoparticles for Decomposition of Organic Dyes in an Aqueous Continuous Phase

ACS Omega
Chen Gelber, S Margel

Abstract

Synthetic organic dyes constitute a major pollutant in wastewater. Here, we describe the synthesis and characterization of N-halamine nanoparticles (NPs) for decomposition of organic dyes from contaminated wastewater. Cross-linked poly(methacrylamide) (PMAA) NPs of hydrodynamic diameters ranging from 11 ± 1 to 161 ± 31 nm were synthesized at room temperature by redox surfactant-free dispersion copolymerization of methacrylamide and the cross-linking monomer N,N'-methylenebis(acrylamide) in an aqueous continuous phase. The effect of various polymerization parameters on the diameter and size distribution of the formed NPs was studied. Additionally, thin coatings composed of cross-linked PMAA NPs were grafted onto oxidized corona-treated polypropylene (PP) films by redox graft polymerization of the monomers in the presence of oxidized PP films. The free and grafted NPs were converted to N-halamine species by chlorination with sodium hypochlorite. The decomposition kinetics of two model organic dyes, methylene blue (MB) and crystal violet (CV), was evaluated for both free and grafted PMAA-Cl NPs. Free cross-linked PMAA-Cl NPs at room temperature, with concentrations of 5 and 0.5 mg/mL, illustrated full decomposition of CV and appro...Continue Reading

References

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Methods Mentioned

BETA
scanning
dynamic light scattering
AFM
scanning electron microscopy
atomic force microscopy

Software Mentioned

Nanoscope Analysis
Image J
ScanAsyst

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