Synthesis and crystal structure of a novel prochiral ketoimine: (E)-acetophenone O-diphenylphosphoryl oxime

Acta Crystallographica. Section C, Structural Chemistry
Sean H Majer, Joseph M Tanski

Abstract

A novel activated prochiral ketoimine, (E)-acetophenone O-diphenylphosphoryl oxime, C(20)H(18)NO(2)P, with an electron-withdrawing substituent on the imine N atom similar to other prochiral ketoimines, has been synthesized and the X-ray crystal stucture determined. The molecules pack together in the solid state via weak intermolecular C-H...O interactions and both face-to-face and edge-to-face π-stacking interactions.

References

Jun 6, 2002·Journal of the American Chemical Society·Takuya KochiJonathan A Ellman
Sep 13, 2002·Journal of the American Chemical Society·Celina GarcíaPatrick J Walsh
Dec 30, 2006·The Journal of Organic Chemistry·Jinglun HuangXiaoming Feng
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Aug 2, 2011·The Journal of Biological Chemistry·Evgeny Bulat, Teresa A Garrett
Mar 8, 2012·Journal of the American Chemical Society·Takahiro NishimuraTamio Hayashi
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick

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