Synthesis and photophysics of some novel imidazole derivatives used as sensitive fluorescent chemisensors.

Journal of Fluorescence
Kanagarathinam SaravananJayaraman Jayabharathi

Abstract

Some novel imidazole derivatives were developed for highly sensitive chemisensors for transition metal ions. Since these compounds are sensitive to different external stimulations such as UV irradiation, heat, increasing pressure and changing the environmental pH causing colour change and so they can be used as a 'multi-way' optically switchable material. A prominent fluorescence enhancement was found in the presence of transition metal ions such as Hg(2+), Pb(2+) and Cu(2+) and this was suggested to result from the suppression of radiationless transitions from the n-π* state in the chemisensors. The existence of C-H….O intramolecular hydrogen bonding in dmphnpi is confirmed by the Natural Bond Orbital analysis (NBO). The Mulliken, NBO charge analysis and the HOMO-LUMO energies were also calculated. The electric dipole moment (μ) and the first-hyperpolarisability (β) value of the investigated molecules have been studied both experimentally and theoretically which reveal that the synthesized molecules have microscopic non-linear optical (NLO) behaviour with non-zero values. Ground and excited state DFT calculation were carried out in order to find out dipole moment and energy.

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Citations

Nov 4, 2010·Journal of Fluorescence·Jayaraman JayabharathiKanagarathinam Saravanan
Jan 29, 2011·Journal of Fluorescence·Jayaraman JayabharathiMarimuthu Venkatesh Perumal
Mar 25, 2011·Journal of Fluorescence·Jayaraman JayabharathiMarimuthu Venkatesh Perumal
Sep 29, 2011·Journal of Fluorescence·Jayaraman JayabharathiNatesan Srinivasan
Nov 10, 2011·Journal of Fluorescence·J JayabharathiM Venkatesh Perumal
Mar 22, 2012·Journal of Fluorescence·Chockalingam KarunakaranKarunamoorthy Jayamoorthy
Jul 31, 2012·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Jayaraman JayabharathiRamalingam Sathishkumar
Apr 5, 2011·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Jayaraman JayabharathiNatesan Srinivasan
Oct 16, 2015·Journal of Computational Chemistry·Yuanyuan LiJinglai Zhang
Oct 8, 2013·Acta Crystallographica. Section E, Structure Reports Online·G DivyaS Lakshmi

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