Synthesis and post-synthetic modification of amine-, alkyne-, azide- and nitro-functionalized metal-organic frameworks based on DUT-5

Dalton Transactions : an International Journal of Inorganic Chemistry
Meike A GotthardtWolfgang Kleist

Abstract

Functionalized 4,4'-biphenyldicarboxylic acid molecules with additional amine, alkyne, azide or nitro groups were prepared and applied in the synthesis of novel metal-organic frameworks and mixed-linker metal-organic frameworks isoreticular to DUT-5. The properties of the frameworks could be tuned by varying the number of functional groups in the materials and the amine groups were employed in post-synthetic modification reactions without changing the framework structure or significantly decreasing the porosity of the materials.

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Citations

May 26, 2017·Chemical Reviews·Li ZhuLin-Bing Sun
Sep 22, 2018·Chemistry : a European Journal·Johannes Bitzer, Wolfgang Kleist
Apr 25, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Babak TahmouresilerdAnthony F Cozzolino
Oct 14, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yingying ZhangLiwei Mi
Nov 15, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Aniruddha DasShyam Biswas
Jun 8, 2018·Inorganic Chemistry·Patrick J LarsonAnthony F Cozzolino

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