Synthesis and reactivity of rare-earth metal phosphaethynolates

Dalton Transactions : an International Journal of Inorganic Chemistry
Sebastian BestgenJose M Goicoechea

Abstract

Over the course of the last six years, research on the synthesis and reactivity of molecular metal phosphaketenes (M-PCO) has gained increasing attention. However, lanthanide complexes of the heavier group 15 cyanate analogue PCO- have not been investigated so far. Herein we present exemplar studies on the nature and reactivity of rare-earth phosphaethynolato-complexes using three characteristic representatives of the rare-earth metals: Y, Nd and Sm. Our investigations comprise both +2 and +3 redox states, and one defined amidinate-based ligand set, as well as novel reaction pathways in the presence of the sequestering agents 18-crown-6 and 2,2,2-crypt.

References

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Sep 1, 2017·Angewandte Chemie·Ying-Zhao MaPeter W Roesky
Nov 21, 2017·Angewandte Chemie·Gabriele HierlmeierJose M Goicoechea
Dec 2, 2017·Angewandte Chemie·Lauren N GrantDaniel J Mindiola
Dec 16, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Robert J GilliardJohn D Protasiewicz
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Citations

Mar 13, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yanbo MeiHansjörg Grützmacher
May 6, 2019·Chemical Communications : Chem Comm·Lauren N GrantDaniel J Mindiola
Jul 28, 2019·Angewandte Chemie·Munmun GhoshFranc Meyer
Jul 25, 2019·Chemistry : a European Journal·Lauren N Grant, Daniel J Mindiola
Jun 6, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Riccardo SuterHansjörg Grützmacher
Jul 1, 2021·Journal of the American Chemical Society·Daniel W N WilsonJose M Goicoechea
Jul 14, 2021·Inorganic Chemistry·Nels T AndersonGregory S Girolami
Aug 5, 2021·Inorganic Chemistry·Akachukwu D ObiRobert J Gilliard
Feb 3, 2022·Dalton Transactions : an International Journal of Inorganic Chemistry·Suma BasappaShubhankar Kumar Bose

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BETA
X-ray
NMR

Software Mentioned

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SCALE3 ABSPACK
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