Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes.

Journal of the American Chemical Society
Neil GrimsterValery V Fokin

Abstract

Highly reactive rhodium(II) N-trifluoromethylsulfonyl azavinyl carbenes are formed in situ from NH-1,2,3-triazoles, triflic anhydride, and rhodium carboxylates. They rapidly and selectively react with olefins, providing cyclopropane carboxaldehydes and 2,3-dihydropyrroles in generally excellent yields and high enantio- and diastereoselectivity.

References

Aug 14, 2003·Chemical Reviews·Huw M L Davies, Rohan E J Beckwith
Jan 25, 2008·Nature·Huw M L Davies, James R Manning
Jul 4, 2008·Organic Letters·Jarosław KalisiakValery V Fokin
Oct 16, 2008·Journal of the American Chemical Society·Tony HorneffValery V Fokin
Oct 1, 2009·Angewandte Chemie·Gerhard Maas
Nov 26, 2009·Journal of the American Chemical Society·Stepan ChuprakovValery V Fokin

❮ Previous
Next ❯

Citations

May 31, 2011·Journal of the American Chemical Society·Stepan ChuprakovValery V Fokin
Jan 12, 2012·Journal of the American Chemical Society·Nicklas Selander, Valery V Fokin
Aug 24, 2012·Journal of the American Chemical Society·Nicklas SelanderValery V Fokin
Oct 10, 2012·Journal of the American Chemical Society·Tomoya MiuraMasahiro Murakami
Mar 13, 2013·Journal of the American Chemical Society·Stepan ChuprakovValery V Fokin
Mar 13, 2013·Journal of the American Chemical Society·Brendan T ParrHuw M L Davies
Apr 24, 2013·Journal of the American Chemical Society·Jillian E Spangler, Huw M L Davies
Aug 7, 2013·Journal of the American Chemical Society·Joshua S AlfordHuw M L Davies
Dec 4, 2013·Journal of the American Chemical Society·Stepan ChuprakovValery V Fokin
Oct 12, 2010·Organic Letters·Jessica Raushel, Valery V Fokin
Jun 23, 2011·Organic Letters·Buddhadeb Chattopadhyay, Vladimir Gevorgyan
Aug 19, 2011·Organic Letters·Mikhail Zibinsky, Valery V Fokin
Jun 7, 2011·Chemical Communications : Chem Comm·Xinxin QiCheol-Min Park
Oct 2, 2015·Chemical Reviews·Kunbing OuyangZhenfeng Xi
May 19, 2017·Chemical Communications : Chem Comm·Subin ChoiCheol-Min Park
Jun 17, 2016·Angewandte Chemie·Minqiang Jia, Shengming Ma
Oct 13, 2015·Chemical Communications : Chem Comm·Yi Shi, Vladimir Gevorgyan
Mar 15, 2018·Angewandte Chemie·Takayuki NakamuroMasahiro Murakami
Feb 24, 2016·Organic & Biomolecular Chemistry·Yuanyuan HuCongyang Wang
May 7, 2016·Chemical Communications : Chem Comm·Nicole S Y LoyCheol-Min Park

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Journal of the American Chemical Society
Nicklas SelanderValery V Fokin
Journal of the American Chemical Society
Nicklas Selander, Valery V Fokin
© 2021 Meta ULC. All rights reserved