Synthesis and rearrangement of a bridged thioamide

Chemical Communications : Chem Comm
Michal Szostak, Jeffrey Aubé

Abstract

The synthesis of a bridged thiolactam is described. This thiolactam is shown to undergo an unusual C-N bond cleavage reaction under conditions of its synthesis. Spectroscopic properties of the thiolactam indicate a considerable degree of twist of the thioamide bond.

References

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Citations

Feb 5, 2014·Chemical Reviews·Michal Szostak, Jeffrey Aubé
Jun 12, 2010·Journal of the American Chemical Society·Michal SzostakJeffrey Aubé
Jan 7, 2016·Organic Letters·Jianpeng WeiXuefeng Jiang
Jun 17, 2015·Organic & Biomolecular Chemistry·Serge ZaretskyAndrei K Yudin
Nov 12, 2010·Organic & Biomolecular Chemistry·Michal Szostak, Jeffrey Aubé
Dec 7, 2013·Organic & Biomolecular Chemistry·Yadong SunJianxiao Li
Mar 3, 2021·Organic & Biomolecular Chemistry·Jigarkumar K VankarGuddeangadi N Gururaja
May 1, 2010·Chemical Reviews·Turan OzturkOlcay Mert
Feb 7, 2019·Journal of the American Chemical Society·Liangbing FuWill R Gutekunst

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