Synthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues

Dalton Transactions : an International Journal of Inorganic Chemistry
Abeje AbebayehuChang-Hee Lee

Abstract

Treatment of meso-malonylidene-(m-benzi)porphyrin and meso-malonylidene-(m-benzi)pentaphyrin with Pd(ii), Au(iii), Ni(ii) and Ag(i) afforded the corresponding metal complexes. The synthesized metal complexes were characterized by spectroscopy including single crystal X-ray, NMR and mass spectrometry. Most metal complexes were stable in solution. The metal complexes showed strong absorption in the near IR region.

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Citations

Sep 23, 2016·Chemical Reviews·Timothy D Lash
Jul 28, 2019·Chemical Communications : Chem Comm·Seong-Jin HongChang-Hee Lee
Jan 4, 2018·The Journal of Organic Chemistry·Sunit KumarMangalampalli Ravikanth
Feb 23, 2017·Chemical Reviews·Bartosz SzyszkoLechosław Latos-Grażyński

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