Synthesis and structure of an aminoethyl-functionalized cyclopentadienyl vanadium(I) dinitrogen complex

Dalton Transactions : an International Journal of Inorganic Chemistry
Guohua LiuBart Hessen

Abstract

Reduction of a V(III) complex [(eta(5),eta(1)-C(5)H(4)CH(2)CH(2)NMe(2))VCl(2)(PMe(3))] in the presence of diphenylacetylene under nitrogen atmosphere yields a novel V(I) dinitrogen-bridged complex {[eta(5)-(C(5)H(4)CH(2)CH(2)NMe(2))]V(PhC[triple bond]CPh)(PMe(3))}(2)(mu-N(2)).

References

Jan 10, 2002·Chemical Reviews·Richard R Schrock
Jun 13, 2002·Chemical Reviews·Stefan Arndt, Jun Okuda
Mar 13, 2003·Journal of the American Chemical Society·Michael D FryzukBrian O Patrick
Feb 12, 2004·Chemical Reviews·Bruce A MacKay, Michael D Fryzuk
Aug 5, 2004·Journal of the American Chemical Society·Lara MorelloMichael D Fryzuk
Sep 18, 2004·Angewandte Chemie·Sandro Gambarotta, Jennifer Scott
Nov 4, 2004·Journal of the American Chemical Society·Jaime A PoolPaul J Chirik
Nov 13, 2004·Journal of the American Chemical Society·Tamara E HannaPaul J Chirik
Sep 15, 2005·Journal of the American Chemical Society·Lara MorelloMichael D Fryzuk
Oct 2, 2008·Journal of the American Chemical Society·Doris PunPaul J Chirik
Feb 15, 1999·Angewandte Chemie·George J P BritovsekDuncan F Wass

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Citations

Sep 11, 2018·Inorganic Chemistry·Yoshiaki KokuboHideki Masuda
May 5, 2020·Chemical Reviews·Devender SinghLeslie J Murray

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