Synthesis, Characterization, and Properties of Diazapyrenes via Bischler-Napieralski Reaction

The Journal of Organic Chemistry
Yi HanYulan Chen

Abstract

Via Bischler-Napieralski cyclization of amide precursors as the key step, a series of diazapyrene derivatives were designed and successfully synthesized. Their crystal structures, optoelectronic properties, and acid-responsive feature were investigated, which demonstrated that the doping of nitrogen atoms to the pyrene framework remarkably modulates their physical and chemical properties.

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