Synthesis of a [2]catenane around a Ru(diimine)3(2+) scaffold by ring-closing metathesis of olefins

Organic Letters
Fabio AricoJean-Pierre Sauvage

Abstract

[reaction: see text] The synthesis of a ruthenium[2]catenane is described. One ring includes two 1,10-phenanthroline moieties, the other a bipyridinic unit. The interlocking ring system was formed by using a double ring closing metathesis reaction. Under irradiation, a rapid and selective decoordination of the bipyridinic fragment was observed, leading to a new catenane in which the metal is only coordinated to the bis-phenanthroline moiety.

References

Feb 20, 2003·Journal of the American Chemical Society·Pierre MobianJean-Pierre Sauvage
Dec 17, 1997·Journal of the American Chemical Society·Aude LivoreilBarbara Ventura

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Citations

Dec 15, 2015·Journal of the American Chemical Society·Ian C Gibbs-HallJ Fraser Stoddart
Sep 9, 2015·Chemical Reviews·Sundus Erbas-CakmakAlina L Nussbaumer
Oct 8, 2009·Journal of the American Chemical Society·Stephen M GoldupJhenyi Wu
May 20, 2005·Organic Letters·Erin N GuidryRobert H Grubbs
Oct 21, 2017·Chemical Communications : Chem Comm·Bilal NisanciÖzgür Altan Bozdemir
Nov 30, 2006·Angewandte Chemie·Euan R KayFrancesco Zerbetto
Jul 16, 2008·Angewandte Chemie·Stephen M GoldupAlexandra M Z Slawin
Sep 2, 2010·Angewandte Chemie·Matthew E BelowichJ Fraser Stoddart
Sep 18, 2012·Chemical Communications : Chem Comm·O Altan BozdemirJ Fraser Stoddart
May 8, 2015·Angewandte Chemie·Guzmán Gil-RamírezAlexander J Stephens
Dec 22, 2009·Organic & Biomolecular Chemistry·Ken Cham-Fai LeungJ Fraser Stoddart
Mar 12, 2009·Journal of the American Chemical Society·David A LeighD Barney Walker
Jun 23, 2009·Chemical Reviews·Sebastien Monfette, Deryn E Fogg
Apr 21, 2005·Journal of the American Chemical Society·Ken C-F LeungJ Fraser Stoddart
May 8, 2013·The Journal of Organic Chemistry·Hajime IwamotoTakeharu Haino
Feb 24, 2015·Chemical Reviews·Da-Hui QuHe Tian
Jun 28, 2007·Journal of the American Chemical Society·Erin N GuidryRobert H Grubbs
Dec 23, 2003·Inorganic Chemistry·Pierre MobianJean-Pierre Sauvage
May 13, 2004·Chemical Reviews·Alexander Deiters, Stephen F Martin
Nov 10, 2005·The Journal of Organic Chemistry·Kelly S ChichakJ Fraser Stoddart

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