Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond

Journal of the American Chemical Society
Daniel J Fox, Robert G Bergman

Abstract

The parent amido iron complex (dmpe)2Fe(H)(NH2) (dmpe = 1,2-bis(dimethylphosphino)ethane), the first such first-row transition metal complex, has been synthesized and characterized spectroscopically and crystallographically. This complex has been found to insert carbon monoxide into the amide N-H bond (rather than the M-N bond) to give trans-(dmpe)2Fe(H)(NHCHO). The mechanism of this transformation has been studied and is believed to occur through an unusual mechanism in which CO behaves as an apparent electrophile.

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Citations

May 31, 2011·Inorganic Chemistry·Leslie D FieldRuaraidh D McIntosh
Apr 30, 2017·Chemical Science·Sidney E Creutz, Jonas C Peters
Jun 24, 2017·Journal of the American Chemical Society·Mathew D AnkerLaurent Maron
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Jul 24, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Madhavan Jaccob, Gopalan Rajaraman
Sep 26, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Joanna R WebbT Brent Gunnoe
Nov 13, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Inmaculada MenaLuis A Oro
Jan 25, 2014·Chemical Communications : Chem Comm·Nathaniel S SickermanA S Borovik
Oct 16, 2019·Nature Chemistry·Daniel E DeRoshaPatrick L Holland
Feb 14, 2007·Chemistry : a European Journal·Andrew J MountfordSimon J Lancaster
Nov 17, 2016·Chemical Society Reviews·Addison N Desnoyer, Jennifer A Love
Mar 19, 2013·Chemistry : a European Journal·Inmaculada MenaLuis A Oro
Aug 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Inmaculada MenaLuis A Oro
Mar 13, 2012·Chemistry, an Asian Journal·Robert KretschmerHelmut Schwarz
Aug 11, 2010·Journal of the American Chemical Society·Jessica L Klinkenberg, John F Hartwig
Aug 3, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Chen SunA S Borovik
Dec 25, 2012·Journal of the American Chemical Society·John S AndersonJonas C Peters
May 7, 2015·Inorganic Chemistry·Leslie D FieldHsiu L Li
Dec 12, 2017·Journal of the American Chemical Society·John J KiernickiNathaniel K Szymczak
Apr 20, 2006·Journal of the American Chemical Society·Suzanne C BartPaul J Chirik

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