Synthesis of a giant 222 carbon graphite sheet

Chemistry : a European Journal
Christopher D SimpsonKlaus Müllen

Abstract

In this paper we present the synthesis and characterization of the so far largest polycyclic aromatic hydrocarbon (PAH), containing 222 carbon atoms or 37 separate benzene units. First a suitable three-dimensional oligophenylene precursor molecule is built up by a sequence of Diels-Alder and cyclotrimerization reactions and then planarized in the final step by oxidative cyclodehydrogenation to the corresponding hexagonal PAH. Structural proof is based on isotopically resolved MALDI-TOF mass spectra and electronic characteristics are studied by UV/Vis spectroscopy.

References

Feb 19, 2002·Chemical Reviews·Alexander J. BerresheimKlaus Müllen
Oct 16, 1998·Angewandte Chemie·Vivekanantan S IyerKlaus Müllen

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Citations

Jan 19, 2007·The Journal of Chemical Physics·Christopher LiuDaniel Neuhauser
Jan 1, 2016·Journal of the American Chemical Society·Tianyue ZhengLuping Yu
Mar 16, 2016·Journal of the American Chemical Society·Uliana BeserKlaus Müllen
Apr 10, 2016·Journal of the American Chemical Society·Nemanja KocićShi-Xia Liu
May 22, 2016·Pharmaceutical Research·Kathryn L SchroederThomas Nann
Aug 2, 2016·Journal of the American Chemical Society·Ho-Wang IpDietmar Kuck
Jan 24, 2017·Environmental Science and Pollution Research International·Ayub KhanXiangke Wang
Aug 27, 2014·Advanced Materials·Xiaodong ZhuangXinliang Feng
Nov 25, 2016·Chemistry, an Asian Journal·Jagarapu Ramakrishna, Parthasarathy Venkatakrishnan
May 30, 2017·Chemical Science·Jongbok LeeLei Fang
Jul 18, 2015·Chemical Society Reviews·Akimitsu NaritaKlaus Müllen
Jun 4, 2017·Chemistry : a European Journal·Johann CorauxFrédéric Chérioux
Nov 8, 2017·Nanoscale·Ang BianJinlong Yang
Nov 3, 2015·Chemical Communications : Chem Comm·Payam PayamyarA Dieter Schlüter
Apr 14, 2018·Chemical Communications : Chem Comm·Sven GrätzLars Borchardt
May 23, 2013·Nature Chemistry·John W Colson, William R Dichtel
Jul 5, 2011·Angewandte Chemie·Thomas BauerA Dieter Schlüter
Apr 13, 2007·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Sibylle Müller, Klaus Müllen
Nov 7, 2018·Chemistry : a European Journal·Marcus RichterReinhard Berger
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Jul 20, 2007·Rapid Communications in Mass Spectrometry : RCM·Anna CristadoroKlaus Müllen
Feb 15, 2019·Chemistry, an Asian Journal·Thomas B J HallNigel T Lucas
Jan 9, 2009·Angewandte Chemie·Junji SakamotoA Dieter Schlüter
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Mar 11, 2010·Advanced Materials·François Diederich, Milan Kivala
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Jul 22, 2005·Angewandte Chemie·Dmitrii F Perepichka, Martin R Bryce
Sep 2, 2005·Angewandte Chemie·Andrew C Grimsdale, Klaus Müllen
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Feb 28, 2019·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Y SaleemP Hawrylak
Jun 25, 2010·Advanced Materials·Dacheng Wei, Yunqi Liu
Jul 7, 2011·Angewandte Chemie·Kostya S Novoselov
Jul 7, 2011·Angewandte Chemie·Andre K Geim

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