Synthesis of boron-iodinated o-carborane derivatives. Water stability of the periodinated monoprotic salt

Inorganic Chemistry
Francesc TeixidorRaikko Kivekäs

Abstract

Boron periodination of o-carborane has been achieved by taking account of the fact that B atoms in the cluster are of two types, i.e., those adjacent to both C atoms and the remainder. The high number of nonequivalent leaving groups opens the possibility through B-C coupling to materials with novel possibilities and to self-assembling due to the enhanced polarizability of the C-H bond. Periodination has accentuated the acidity of the carborane, and monoprotic salts are stable in water.

References

Dec 13, 1996·The Journal of Organic Chemistry·Rajiv R. SrivastavaD. Scott Wilbur
Jul 21, 2005·Journal of the American Chemical Society·Francesc TeixidorClara Viñas

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Citations

Jul 26, 2011·Chemical Reviews·Matthias Scholz, Evamarie Hey-Hawkins
Oct 19, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Albert VacaClara Viñas
Aug 12, 2016·Chemical Communications : Chem Comm·Fangrui ZhengGuochen Jia
Jul 5, 2018·Chemistry : a European Journal·Yang GaoGuo-Xin Jin
Apr 27, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yangjian QuanZuowei Xie
Mar 4, 2020·Physical Chemistry Chemical Physics : PCCP·Maria de Las Nieves PiñaAntonio Frontera
May 16, 2019·Chemical Society Reviews·Yangjian Quan, Zuowei Xie
Apr 20, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Francesc TeixidorClara Viñas
Nov 18, 2017·Chemistry : a European Journal·Yangjian QuanZuowei Xie
Aug 10, 2013·Journal of the American Chemical Society·Zaozao QiuZuowei Xie
Oct 23, 2014·Journal of the American Chemical Society·Yangjian Quan, Zuowei Xie
Mar 10, 2015·Journal of the American Chemical Society·Yangjian Quan, Zuowei Xie
Aug 28, 2021·Chemical Science·H D A Chathumal JayaweeraDmitry V Peryshkov
Jan 27, 2022·Chemical Communications : Chem Comm·Sophia E Hollow, Timothy C Johnstone

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