Synthesis of elusive chloropnictenium ions

Chemistry : a European Journal
Christian Hering-JunghansAxel Schulz

Abstract

This work describes the synthesis and full characterization of elusive chloropnictenium ion salts of the type [(R)Ar*N(SiMe)ECl][A] ((R)Ar* = 2,6-(CHPh2)-4-R-C6H2, R = Me, tBu; E = Sb, Bi; A(-) = GaCl4, Al(OCH(CF3)2)4). In these species the cation is significantly stabilized by weak arene interactions to flanking phenyl groups of the (R)Ar* moiety. In this context the bonding situation has been studied by computational means and the reactivity towards the Lewis base 4-dimethylaminopyridine (dmap) was investigated.

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Citations

Aug 22, 2015·Chemical Society Reviews·Deborah L Kays
Oct 16, 2015·Chemistry : a European Journal·Jonas BresienAlexander Villinger
Aug 4, 2015·Chemical Communications : Chem Comm·C Hering-JunghansA Villinger
Feb 26, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Christian Hering-JunghansAlexander Villinger
Oct 13, 2016·Chemistry : a European Journal·Hannah Dengel, Crispin Lichtenberg
Mar 9, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·R J SchwammC M Fitchett
Nov 28, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Axel SchulzAlexander Villinger
Jan 3, 2019·Chemistry, an Asian Journal·Ryan J SchwammMartyn P Coles
Apr 30, 2020·Physical Chemistry Chemical Physics : PCCP·Ana-Maria FritzscheMichael Mehring
May 20, 2020·Chemistry : a European Journal·Jacqueline Ramler, Crispin Lichtenberg
Sep 29, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Henrik BeerAlexander Villinger
Apr 17, 2021·Chemical Communications : Chem Comm·Crispin Lichtenberg
Jan 1, 2020·Inorganic Chemistry·Jacqueline RamlerCrispin Lichtenberg

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