Synthesis of Ln(III) chloride tetraphenylporphyrin complexes

Inorganic Chemistry
Timothy J FoleyJames M Boncella

Abstract

The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

Citations

May 8, 2008·Sensors·Carrie L AmiotJulia Xiaojun Zhao
May 3, 2012·Chemical Communications : Chem Comm·Eui-Jong KimWoo-Dong Jang
Dec 1, 2006·The Journal of Physical Chemistry. a·Meng-Sheng LiaoMing-Ju Huang

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