Synthesis of Nanoscale Coordination Polymers in Femtoliter Reactors on Surfaces

ACS Nano
M GuardingoD Ruiz-Molina

Abstract

In the present work, AFM-assisted lithography was used to perform the synthesis of a coordination polymer inside femtoliter droplets deposited on surfaces. For this, solutions of the metal salt and the organic ligand were independently transferred to adjacent tips of the same AFM probe array and were sequentially delivered on the same position of the surface, creating femtoliter-sized reaction vessels where the coordination reaction and particle growth occurred. Alternatively, the two reagents were mixed in the cantilever array by loading an excess of the inks, and transferred to the surface immediately after, before the precipitation of the coordination polymer took place. The in situ synthesis allowed the reproducible obtaining of round-shaped coordination polymer nanostructures with control over their XY positioning on the surface, as characterized by microscopy and spectroscopy techniques.

References

Jul 13, 2006·Journal of the American Chemical Society·William J RieterWenbin Lin
Jan 30, 2008·Angewandte Chemie·Inhar ImazDaniel Ruiz-Molina
Jul 2, 2008·Inorganic Chemistry·Florence VolatronTalal Mallah
Sep 20, 2008·Chemical Communications : Chem Comm·Thibaut ForestierJean-François Létard
Jan 30, 2010·Chemical Society Reviews·Ashok K GanguliSonalika Vaidya
Mar 11, 2010·Advanced Materials·Elena BellidoDaniel Maspoch
May 28, 2010·Inorganic Chemistry·José Ramón Galán-MascarósMarcelo Ceolin
Feb 2, 2011·Journal of the American Chemical Society·Carlos CarbonellDaniel Maspoch
Mar 18, 2011·Chemical Communications : Chem Comm·E BellidoD Ruiz-Molina
May 6, 2011·Chemical Society Reviews·Azzedine BousseksouWilliam Nicolazzi
Feb 10, 2012·Macromolecular Rapid Communications·Zhuang XieZijian Zheng
May 30, 2012·Advanced Materials·Paolo FalcaroCara M Doherty
Jan 2, 2013·Proceedings of the National Academy of Sciences of the United States of America·Guoliang LiuChad A Mirkin
Feb 14, 2013·ACS Nano·Boya RadhaChad A Mirkin
May 4, 2013·Chemical Science·Guoliang LiuChad A Mirkin
May 28, 2013·Chemical Reviews·Valentin Valtchev, Lubomira Tosheva
Jul 19, 2013·Nature Communications·Carlos CarbonellDaniel Maspoch
Dec 18, 2013·Chemical Society Reviews·Josep Puigmartí-Luis
May 8, 2014·Chemical Society Reviews·Paolo FalcaroMark J Styles
Sep 10, 2014·Chemical Communications : Chem Comm·M GuardingoD Ruiz-Molina
Oct 7, 2014·Chemistry : a European Journal·Fernando NovioDaniel Ruiz-Molina
Jan 20, 2015·Nature Communications·Aleksandr PerevedentsevDonal D C Bradley

❮ Previous
Next ❯

Citations

Jul 20, 2016·Chemical Communications : Chem Comm·Elizabeth E OselandPatrick R Unwin
Jul 30, 2016·Chemical Communications : Chem Comm·M GuardingoD Ruiz-Molina
Mar 11, 2017·Nano Letters·Shivaranjan RaghuramanJonathan R Felts
Jun 26, 2018·Advanced Materials·Jordyn AtwaterMichael Hirtz
Jun 15, 2018·Chemistry : a European Journal·F NadorF Novio
Sep 5, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Arnab MandalDebasis Das

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Christine JérômeAnne-Sophie Duwez
Journal of Combinatorial Chemistry
Philip F HughesJose S Mendoza
© 2021 Meta ULC. All rights reserved