Synthesis of novel palladacycles and their application in Heck and Suzuki reactions under aerobic conditions

Organic Letters
Zhengchang XiongZhen Yang

Abstract

[reaction: see text] Design and synthesis of a novel family of furancarbothioamide-based palladacycles are reported herein. These palladacycles are thermally stable, not sensitive to air or moisture, and are applied effectively in the Heck reaction of aryl halides with terminal olefins and in the Suzuki reaction of aryl halides with arylboronic acids. These reactions were performed under aerobic conditions, leading to turnover numbers (TONs) up to 1 x 10(5).

References

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Citations

Dec 15, 2007·Journal of Mass Spectrometry : JMS·Li RuiWei Yuquan
Oct 23, 2015·Organic Letters·Takayuki YamauchiToshiaki Murai
Feb 2, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Alpesh K SharmaAjai K Singh
Jun 25, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Satyendra KumarAjai K Singh
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Dec 22, 2009·Chemistry : a European Journal·Egle M BeccalliGianluigi Broggini
Jul 3, 2010·Organic & Biomolecular Chemistry·Andrés A Poeylaut-Palena, Ernesto G Mata
Sep 14, 2010·Organic & Biomolecular Chemistry·Carine DieboldClaude Le Drian
Jan 27, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Chi WangChi-Tien Chen
Sep 1, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Martin J D ChampionJames D E T Wilton-Ely
Mar 9, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Elangovan SindhujaYu Liu
Jan 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Arun KumarAjai K Singh
Nov 22, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Gyandshwar Kumar RaoAjai Kumar Singh
Aug 30, 2008·Journal of Combinatorial Chemistry·Nengdong WangZhen Yang
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Jun 9, 2005·Chemical Reviews·Jairton DupontJohn Spencer
Jul 16, 2005·The Journal of Organic Chemistry·Leifang LiuYanguang Wang

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