Synthesis of Organosilyl-Functionalized Cage-Type Germanoxanes Containing Fluoride Ions

Chemistry : a European Journal
Naoto SatoKazuyuki Kuroda

Abstract

Eight corners of a double-four ring cage-type germanoxane, containing a fluoride ion, were successfully silylated by the combination of chlorosilanes and silazanes. Three different silyl groups, trimethylsilyl, dimethylsilyl, and dimethylvinylsilyl, were attached on the corners of germanoxane cage. The solubility and reactivity of the cage modified with dimethylvinylsilyl groups were significantly increased, allowing for further reaction. Hydrosilylation reaction between dimethylvinylsilylated cage geramanoxanes and dimethylsilylated cage siloxanes afforded porous solids. Functionalization of the corners of germanoxanes with silyl groups should provide valuable building blocks in various functional materials.

References

Dec 14, 2001·Journal of the American Chemical Society·J PlévertM O'Keeffe
Oct 26, 2002·Chemical Communications : Chem Comm·Luis A VillaescusaRussell E Morris
Aug 6, 2003·Angewandte Chemie·Alan R BassindaleMark E Light
Jul 15, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Luis A VillaescusaPhilip Lightfoot
Oct 20, 2004·Accounts of Chemical Research·R MurugavelC N R Rao
Nov 30, 2004·Chemical Communications : Chem Comm·Atsushi Shimojima, Kazuyuki Kuroda
Jul 19, 2006·Angewandte Chemie·Ramaswamy MurugavelAlexander Steiner
Nov 2, 2006·Journal of the American Chemical Society·Kirsten E ChristensenXiaodong Zou
Feb 7, 2007·Chemical Communications : Chem Comm·Viswanathan BaskarRichard E P Winpenny
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Feb 5, 2008·Chemistry, an Asian Journal·Hideki KugeKazuyuki Kuroda
Sep 11, 2008·Chemistry : a European Journal·Atsushi ShimojimaKazuyuki Kuroda
Oct 8, 2009·Journal of the American Chemical Society·Xiaoyan RenYing Xu
Oct 13, 2009·Inorganic Chemistry·Charlotte BonneauXiaodong Zou
Mar 17, 2010·Chemical Reviews·David B CordesFranck Rataboul
Nov 11, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Vadapalli ChandrasekharE Carolina Sañudo
Dec 20, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Peter G TaylorSimon J Coles
Mar 13, 2014·Inorganic Chemistry·Alok Ch Kalita, Ramaswamy Murugavel
Aug 15, 2014·Inorganic Chemistry·Alok Ch KalitaRamaswamy Murugavel
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
May 6, 2015·Angewandte Chemie·Jie LiangJunliang Sun
May 7, 2015·Chemical Society Reviews·Pavla EliášováJiří Čejka
Dec 19, 2017·Angewandte Chemie·Donghui JoSuk Bong Hong

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Citations

May 29, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Taiki HayashiKazuyuki Kuroda

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