Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C-H bond activation at room temperature

Chemical Communications : Chem Comm
G VlahopoulouT Beweries

Abstract

Rhodium(iii) thiophosphinito pincer hydrido complexes were synthesised by C-H activation under exceptionally mild conditions at room temperature without additional base or irradiation and fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. C-H activation under these mild conditions contrasts with the reactivity of related systems with POCOP ligands.

References

Mar 12, 2011·Chemical Reviews·Jongwook ChoiAlan S Goldman
Mar 12, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Samuel D TimpaOleg V Ozerov
Mar 1, 2012·Inorganic Chemistry·Michael FindlaterMaurice Brookhart
Feb 13, 2018·Chemical Society Reviews·Eduardo Peris, Robert H Crabtree
Oct 15, 2001·Angewandte Chemie·Martin Albrecht, Gerard van Koten

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Citations

Oct 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sandeep Kaur-GhumaanTorsten Beweries

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Methods Mentioned

BETA
NMR
X-ray

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