Synthesis of uranium-in-cryptand complexes

Chemical Communications : Chem Comm
Daniel N HuhWilliam J Evans

Abstract

The facile encapsulation of U(iii) and La(iii) by 2.2.2-cryptand (crypt) using simple starting materials is described. Addition of crypt to UI3 and LaCl3 forms the crystallographically-characterizable complexes, [U(crypt)I2]I and [La(crypt)Cl2]Cl. In the presence of water, the U(iii)-aquo adducts, [U(crypt)I(OH2)][I]2 and [U(crypt)I(OH2)][I][BPh4], can be isolated.

References

Jan 15, 2008·Angewandte Chemie·Peter B HitchcockAndrey V Protchenko
Sep 17, 2011·Journal of the American Chemical Society·Matthew R MacDonaldWilliam J Evans
May 16, 2012·Journal of the American Chemical Society·Matthew R MacDonaldWilliam J Evans
May 24, 2013·Journal of the American Chemical Society·Matthew R MacDonaldWilliam J Evans
Jun 4, 2014·Angewandte Chemie·Henry S La PierreKarsten Meyer
Apr 9, 2015·Journal of the American Chemical Society·Akhila N W Kuda-WedagedaraMatthew J Allen
Jan 26, 2016·Nature·Dominik P HalterKarsten Meyer
Feb 20, 2018·Inorganic Chemistry·Chad T PalumboWilliam J Evans
Apr 21, 2018·Chemical Science·Tyler C JenksMatthew J Allen

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Citations

Oct 22, 2020·Angewandte Chemie·Dieuwertje K ModderMarinella Mazzanti
May 18, 2021·Chemical Science·Dieuwertje K ModderMarinella Mazzanti
Jun 24, 2021·Inorganic Chemistry·Anthony W McDonaghCaterina F Ramogida
Nov 24, 2020·Inorganic Chemistry·Daniel N HuhWilliam J Evans
Dec 23, 2021·Chemical Communications : Chem Comm·Conrad A P GoodwinWilliam J Evans

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Methods Mentioned

BETA
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