Synthesis, reactivity, and ligand properties of a stable alkyl carbene

Journal of the American Chemical Society
Vincent LavalloGuy Bertrand

Abstract

Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments.

References

Nov 28, 2001·The Journal of Organic Chemistry·J KrysiakG Bertrand
Oct 3, 2002·Journal of the American Chemical Society·Emmanuelle DespagnetGuy Bertrand
Dec 21, 2002·The Journal of Organic Chemistry·Qing YeMaitland Jones
Feb 1, 2003·The Journal of Organic Chemistry·Xavier CattoënGuy Bertrand
Dec 4, 2003·Journal of the American Chemical Society·Eri IwamotoHideo Tomioka
Feb 5, 2004·Journal of the American Chemical Society·Xavier CattoënGuy Bertrand
Apr 1, 2004·Angewandte Chemie·Wolfgang Kirmse

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Citations

Mar 23, 2012·Nature Chemistry·Jonathan P Moerdyk, Christopher W Bielawski
Mar 10, 2007·Chemical Communications : Chem Comm·Silvia Gómez-BujedoJosé M Lassaletta
Oct 3, 2008·Chemical Communications : Chem Comm·Guido D FreyGuy Bertrand
Sep 22, 2012·Science·Fabian DielmannGuy Bertrand
Jul 7, 2015·Future Medicinal Chemistry·Siddappa A PatilMatthias Tacke
Jan 21, 2017·Chemistry : a European Journal·Janell K MahoneyGuy Bertrand
Jul 1, 2016·Chemistry : a European Journal·Ursula S D PaulUdo Radius
Jan 1, 2006·Journal of Organometallic Chemistry·Rodolphe JazzarGuy Bertrand
Oct 1, 2004·Angewandte Chemie·Roger W AlderJan Schütz
Dec 18, 2014·Accounts of Chemical Research·Michèle Soleilhavoup, Guy Bertrand
Jul 7, 2015·Chemical Communications : Chem Comm·Manuel IglesiasLuis A Oro
Jul 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Samantha G EavesPaul J Low
Mar 25, 2016·Chemical Communications : Chem Comm·Zachary R McCartyChristopher W Bielawski
Jul 17, 2007·Angewandte Chemie·Marion HeckenrothMartin Albrecht
Aug 27, 2015·Chemistry : a European Journal·Tim SchulzUlrich Siemeling
Apr 5, 2017·Angewandte Chemie·Mohand MelaimiGuy Bertrand
Jul 28, 2006·Angewandte Chemie·Thomas T Tidwell
Apr 19, 2007·Chemistry, an Asian Journal·Jason D MasudaGuy Bertrand
Jul 31, 2007·Angewandte Chemie·Alan DeHopeGuy Bertrand
Oct 20, 2007·Angewandte Chemie·Alyson L Kenward, Warren E Piers
Apr 10, 2008·Angewandte Chemie·F Ekkehardt Hahn, Mareike C Jahnke
Jun 23, 2009·Angewandte Chemie·Olivier BackGuy Bertrand
Aug 6, 2009·Chemistry : a European Journal·Marion HeckenrothMartin Albrecht
Sep 14, 2010·Angewandte Chemie·Mohand MelaimiGuy Bertrand
Feb 1, 2006·Angewandte Chemie·F Ekkehardt Hahn
Jul 12, 2011·Chemical Science·David MartinGuy Bertrand
Nov 29, 2013·Chemistry : a European Journal·Florie LavigneAntoine Baceiredo
Feb 16, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Henning SteinertViktoria H Gessner
Aug 14, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Martin Albrecht
Apr 8, 2011·Angewandte Chemie·Gaël UngGuy Bertrand
May 16, 2018·Chemistry, an Asian Journal·Yves Canac
Oct 17, 2018·Nature Chemistry·Ryo NakanoGuy Bertrand
Jan 1, 2011·New Journal of Chemistry = Nouveau Journal De Chimie·Alan DehopeGuy Bertrand
Aug 16, 2008·Angewandte Chemie·Matthew AsayGuy Bertrand
Aug 7, 2012·Chemical Communications : Chem Comm·Tim SchulzUlrich Siemeling
Jun 22, 2013·Chemical Society Reviews·David J Nelson, Steven P Nolan

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