Synthesis, structure and luminescent properties of yttrium benzene dicarboxylates with one- and three-dimensional structure

Dalton Transactions : an International Journal of Inorganic Chemistry
A Thirumurugan, Srinivasan Natarajan

Abstract

The synthesis and structure of two yttrium benzene dicarboxylates, 1 is proportional to [[Y2(C12N2H8)2(C8H4O4)3].H2O], I and 3 is proportional to [[Y2(C12N2H8)2(C8H4O4)3]], II with one- and three-dimensional structure has been accomplished employing hydrothermal methods in the presence of 1,10-phenanthroline. While I is formed with phthalic aid (1,2-BDC), II is formed using isophthalic acid (1,3-BDC). Both the structures appear to have comparable building units, an eight-membered ring and a paddle-wheel arrangement, connected through the carboxylic acid. The 1,10-phenanthroline, connected to Y as a secondary ligand, occupies the inter-chain spaces in I, and projects into the channels in II. The channels in II are inter-connected. Photoluminescence studies indicate that both I and II exhibit a bathochromic shift with respect to the acids (1,2-BDC and 1,3-BDC) and a hypsochromic shift with respect to 1,10-phenanthroline. Both the compounds exhibit reasonable pi...pi interactions.

References

Mar 17, 2004·Angewandte Chemie·C N R RaoR Vaidhyanathan

❮ Previous
Next ❯

Citations

Jan 1, 2007·Acta Crystallographica. Section E, Structure Reports Online·Peng-Tao MaMing-Xue Li
Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Sumei YaoQiuxia Han
Dec 27, 2011·Acta Crystallographica. Section E, Structure Reports Online·Zhongyue Li, Kun Liu
Oct 2, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Hua WuZhong-Min Su
May 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Hua WuHong-Ye Bai
May 21, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Bao-Xia DongQiang Xu
Sep 3, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Bo LiThomas C W Mak
Aug 16, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu-Ling WangQing-Yan Liu
May 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Yan-Li GaiMao-Chun Hong
Aug 16, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Beibei GuoGang Li
Sep 11, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Partha MahataSrinivasan Natarajan
May 17, 2012·Acta Crystallographica. Section E, Structure Reports Online·Kun Liu
Aug 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Pavel A DemakovDanil N Dybtsev
Jul 14, 2006·The Journal of Physical Chemistry. B·Partha MahataSrinivasan Natarajan

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.