Synthesis, structure, and reactivity of naphthalyne-Co2(CO)6 complexes

Journal of the American Chemical Society
N IwasawaJun Takaya

Abstract

Synthesis of naphthalyne-Co2(CO)6 complexes, the first example of the aryne-Co2(CO)6 complex, was achieved via cyclization of acyclic alkyne-Co2(CO)6 complex precursors containing an allylsilane and an aldehyde moiety followed by dehydration. Unique reactivities of the complexes toward oxygen to give carboxylic acid derivatives and toward alkynes to give cyclopentadienone derivatives were also disclosed.

References

Sep 21, 2002·Chemical Communications : Chem Comm·T SugiharaM Nishizawa

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Citations

Mar 10, 2011·Chemistry : a European Journal·Sheida AmiralaeiJames R Green
Feb 7, 2018·The Journal of Organic Chemistry·Anna G LyapunovaIrina A Balova
Nov 19, 2019·ACS Omega·Mariam A MehdiJames R Green

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