Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene

Chemical Communications : Chem Comm
Sakya S SenDietmar Stalke

Abstract

Reaction of LSi-SiL (1) (L = PhC(NtBu)(2)) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.

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Citations

Jan 5, 2012·Accounts of Chemical Research·Sakya S SenHerbert W Roesky
Oct 1, 2011·Inorganic Chemistry·Shabana KhanDietmar Stalke
Jan 13, 2012·Chemical Communications : Chem Comm·Shabana KhanHerbert W Roesky
Jun 19, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·V S V S N SwamySakya S Sen
Jul 30, 2014·Chemical Communications : Chem Comm·Syed Usman AhmadShigeyoshi Inoue
Feb 28, 2014·Angewandte Chemie·Anukul JanaDavid Scheschkewitz
May 24, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Tomohiro SugaharaNorihiro Tokitoh
Jul 6, 2011·Angewandte Chemie·Kai AbersfelderDavid Scheschkewitz
Mar 16, 2013·Angewandte Chemie·Daniel KratzertDietmar Stalke
Jul 5, 2018·Journal of Molecular Modeling·Ann-Christin AndresMichael Springborg
Jan 26, 2012·Chemistry : a European Journal·Hui-Xian YeongCheuk-Wai So
Oct 31, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Zsolt BenedekTamás Veszprémi
Sep 20, 2017·Chemistry : a European Journal·Crispin R W ReinholdThomas Müller
Jan 29, 2021·Journal of the American Chemical Society·Yilin ChenHerbert W Roesky
May 28, 2021·Chemical Science·Takahiro Sasamori
Aug 10, 2021·Chemical Society Reviews·Kei Ota, Rei Kinjo
Jun 4, 2020·Inorganic Chemistry·Jiancheng LiHerbert W Roesky
May 8, 2019·The Journal of Physical Chemistry. a·Takako KudoNikita Matsunaga
Feb 2, 2019·Journal of the American Chemical Society·Tomohiro SugaharaNorihiro Tokitoh
Sep 22, 2021·Angewandte Chemie·Yi DingHerbert W Roesky

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