Synthesis, Structure, and Vibrational Properties of [Ph4 P]2 NpO2 Cl4 and [Ph4 P]2 PuO2 Cl4 Complexes

Inorganic Chemistry
David D Schnaars, Richard E Wilson

Abstract

The synthesis, structure, and vibrational properties are presented for an isostructural series of Np(VI) and Pu(VI) complexes of the form [Ph4P]2AnO2Cl4, where An = Np(VI) or Pu(VI). The reported complexes are readily synthesized in ambient laboratory conditions, and their molecular structures were determined using single crystal X-ray diffraction. Their vibrational spectra were studied using a combination of Raman and FT-IR vibrational spectroscopies. Analysis of the vibrational spectra and force constants highlight the periodic properties associated with the actinide contraction and filling of the 5f electronic shells. Additionally, we have assessed the utility of these complexes as conveniently synthesized starting materials for non-aqueous synthesis of transuranium molecules and materials.

References

May 31, 2002·Acta Crystallographica. Section B, Structural Science·Frank H Allen
May 29, 2007·Chemical Communications : Chem Comm·Andrew J GauntMary P Neu
Aug 22, 2008·Inorganic Chemistry·Andrew J GauntMary P Neu
Feb 14, 2009·Chemical Communications : Chem Comm·Stéphanie M CornetNikolas Kaltsoyannis
Jan 1, 2007·Acta Crystallographica. Section E, Structure Reports Online·Marianne P Wilkerson, Brian L Scott
Oct 28, 2011·Inorganic Chemistry·Grigory AndreevPhilippe Moisy
Jan 17, 2012·Angewandte Chemie·Matthew J PolinskiThomas E Albrecht-Schmitt
May 5, 2012·Inorganic Chemistry·Stefan G MinasianDavid K Shuh
Nov 8, 2012·Chemical Reviews·Matthew B Jones, Andrew J Gaunt
Nov 22, 2013·Inorganic Chemistry·David D Schnaars, Richard E Wilson
Oct 10, 2014·Inorganic Chemistry·David D Schnaars, Richard E Wilson
Oct 30, 2015·The Journal of Physical Chemistry. a·Monica VasiliuDavid A Dixon
Jan 20, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Nikolas Kaltsoyannis
Jul 13, 2017·Journal of the American Chemical Society·Robert G SurbellaChristopher L Cahill
Aug 31, 2017·Chemical Reviews·Polly L ArnoldOlaf Walter

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Citations

Sep 7, 2018·Chemical Communications : Chem Comm·Korey P CarterJohn K Gibson
May 30, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jennifer L BjorklundTori Z Forbes
Jul 18, 2019·Chemical Communications : Chem Comm·Mikaela M PyrchTori Z Forbes
Dec 6, 2019·Chemistry : a European Journal·Evan L ThomasRichard E Wilson
May 10, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Mikaela M PyrchTori Z Forbes

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