Abstract
A series of Ln-Ag heterometal-organic frameworks based on 4-hydroxylpyridine-2,6-dicarboxylic acid (H(3)CAM) with formulas {LaAg(2)(CAM)(HCAM)(H(2)O)(2)}(n) (1), {LnAg(HCAM)(2)(H(2)O)(3)}(n) (Ln = Pr, 2; Nd, 3; Sm, 4; Eu, 5), and {LnAg(3)(CAM)(2)(H(2)O)}(n) (Ln = Gd, 6; Tb, 7; Dy, 8; Tm, 9; Yb, 10), have been synthesized with the hydrothermal reaction of Ln(OH)(3), Ag(2)O, and H(3)CAM at 160 degrees C. The single-crystal X-ray diffraction analyses reveal that three kinds of structures are exclusively governed by the size of lanthanide ions and the progression of structures is mainly ascribed to the lanthanide contraction effect. Compound 1 consists of a 3D network with an alpha-polonium-like Ag(+)-homometallic net and helical La(3+) chain. Compounds 2-5 display a 2D honeycomb-like structure with 18-membered Ln(3)Ag(3)O(12) motifs, and compounds 6-10 can be described as a sandwich-like 3D framework built of a 3D Ag(+)-homometallic net and 2D Ln(3+)-4(4) layer. In 4 (Sm), 5 (Eu), 7 (Tb), and 8 (Dy) samples, the efficient energy transfer from CAM to Ln(III) ions was observed, which results in the typical intense emissions of corresponding Ln(III) ions in the visible region, and the strongest emissions are (4)G(5/2) --> (6)H(7/2) (...Continue Reading
References
Feb 24, 2001·Chemistry : a European Journal·A DeiL Sorace
Sep 18, 2001·Inorganic Chemistry·J P CostesF Nicodème
Oct 24, 2001·Inorganic Chemistry·J.-P. CostesJ.-P. Laurent
Apr 11, 2002·Journal of the American Chemical Society·Chuan-De WuJin-Shun Huang
Jun 13, 2002·Chemical Reviews·Cristiano Benelli, Dante Gatteschi
Aug 31, 2002·Chemistry : a European Journal·Jean-Pierre Costes, Franck Nicodème
Dec 20, 2002·Angewandte Chemie·Jean-Pierre CostesMarc Verelst
Feb 22, 2003·Angewandte Chemie·Bin ZhaoGeng-Lin Wang
Apr 15, 2003·Inorganic Chemistry·Sadafumi NishiharaTakayoshi Nakamura
Apr 16, 2003·Inorganic Chemistry·Hongwei HouYaoting Fan
Jul 2, 2003·Angewandte Chemie·Stephan T Hatscher, Werner Urland
Jul 16, 2003·Accounts of Chemical Research·Christine E PlecnikSheldon G Shore
Aug 14, 2003·Journal of the American Chemical Society·Peter B GloverZoe Pikramenou
Sep 3, 2003·Inorganic Chemistry·María Hernández-MolinaMiguel Julve
Oct 2, 2003·Journal of the American Chemical Society·Thorfinnur GunnlaugssonAndrew J Harte
Dec 18, 2003·Journal of the American Chemical Society·Daniel ImbertClaude Piguet
Feb 26, 2004·Journal of the American Chemical Society·Weisheng LiuLiufang Wang
Mar 12, 2004·Journal of the American Chemical Society·Bin ZhaoZonghui Jiang
Jul 15, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomas A MillerStephen Faulkner
Jul 30, 2004·Journal of the American Chemical Society·Andrew P BassettZoe Pikramenou
Nov 26, 2004·Journal of the American Chemical Society·Bin ZhaoZong-Hui Jiang
Jun 21, 2005·Inorganic Chemistry·Graham M DaviesMichael D Ward
Oct 1, 2005·Chemistry : a European Journal·Bin ZhaoZong-Hui Jiang
Nov 22, 2005·Inorganic Chemistry·Ricardo BaggioAlberto Rizzi
Dec 24, 2005·Chemical Communications : Chem Comm·Youfu ZhouXintao Wu
Jan 13, 2006·Journal of the American Chemical Society·Lindsay E Roy, Timothy Hughbanks
Feb 2, 2006·Journal of the American Chemical Society·Fumihito MoriHiroyuki Nojiri
Apr 20, 2006·Chemical Communications : Chem Comm·Juan-Manuel HerreraStephen Faulkner
Aug 15, 2006·Inorganic Chemistry·Wai-Fun YeungWing-Tak Wong
Oct 13, 2006·Inorganic Chemistry·Olivier GuillouNicolas Kerbellec
Nov 7, 2006·Inorganic Chemistry·Xiaojun Gu, Dongfeng Xue
Mar 14, 2007·Angewandte Chemie·Thazhe K PrasadJean-Pierre Costes
Apr 27, 2007·Inorganic Chemistry·Ying WangShi-Ping Yan
Jul 3, 2007·Inorganic Chemistry·Xiao-Qing ZhaoShi-Ping Yan
Sep 14, 2007·Inorganic Chemistry·Bin LiuLi-Min Zheng
Nov 16, 2007·Journal of the American Chemical Society·Shengchang XiangXudong Zhang
Feb 26, 2008·Angewandte Chemie·Xiang-Jian KongLan-Sun Zheng
Apr 4, 2008·Chemistry, an Asian Journal·Nobuhiko IkiHitoshi Hoshino
Oct 31, 2008·Inorganic Chemistry·Hong-Ling GaoShi-Ping Yan
Feb 24, 2009·Chemistry : a European Journal·Soumaila ZebretJosef Hamacek
Mar 20, 2009·Inorganic Chemistry·Zhi ChenYou Song
May 23, 2009·Chemical Communications : Chem Comm·Bin ZhaoDai-Zheng Liao
Citations
Jan 16, 2014·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Hatice VuralM Serkan Soylu
Mar 6, 2012·Inorganic Chemistry·Jin-Cheng WuMei-Xiang Wang
Mar 13, 2013·Inorganic Chemistry·Alla DikhtiarenkoJosé Gimeno
Jul 4, 2013·Inorganic Chemistry·Jing-Min ZhouPeng Cheng
Oct 28, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Ya-guang SunFrancis Verpoort
May 20, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Hai-Lin CuiDan Li
Jun 1, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yun-Nan GongDi-Chang Zhong
Apr 1, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Wen-Ya WuPeng Cheng
May 6, 2015·Chemical Communications : Chem Comm·Hang XuBin Zhao
Aug 16, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Debal Kanti Singha, Partha Mahata
Aug 17, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Manesh KumarAmanpreet Kaur Jassal
Aug 30, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Qing ZhaoBin Zhao
Jan 26, 2013·Chemistry : a European Journal·Huanhuan LiPeng Cheng
Jun 18, 2011·Luminescence : the Journal of Biological and Chemical Luminescence·Zhen-Zhong YanYong-Qiang Lin
May 27, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Dongdong YangMiaoli Zhu
Jun 19, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Ping ZhangJian-Wen Cheng
Sep 13, 2013·Chemistry : a European Journal·Yun WangJian-Fang Ma
Oct 22, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Xin YouYa-Guang Sun
Dec 25, 2010·Chemical Society Reviews·João RochaDuarte Ananias
Nov 21, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Yin-Ling HouBin Zhao
Oct 16, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Qing ZhaoBin Zhao
Jul 11, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Junkuo GaoQichun Zhang
Jul 18, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Debraj SahaSubratanath Koner
Apr 10, 2019·Polymers·Yun XuJi-Min Zheng
Dec 15, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Qing ZhaoPeng Cheng
Jan 8, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Yin-Ling HouJian-Zhong Cui
May 24, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Ya-Guang SunFrancis Verpoort
Mar 1, 2012·Journal of the American Chemical Society·Shou-Tian ZhengXianhui Bu
Nov 13, 2010·Inorganic Chemistry·Mengyuan LiSong Gao
Mar 19, 2014·Inorganic Chemistry·Yunshan ZhouZonghai Shi
Jun 18, 2014·Inorganic Chemistry·Min ChenMiao Du
May 20, 2015·Inorganic Chemistry·Zhi-Lei WuBin Zhao
Apr 25, 2020·Inorganic Chemistry·Qiutong XuPeng Cheng