Synthesis using aromatic homolytic substitution--recent advances

Chemical Society Reviews
W Russell Bowman, John M D Storey

Abstract

This critical review aims at presenting recent developments in intramolecular aromatic homolytic substitution which has become one of the common methodologies in modern synthesis. The application of Bu3SnH-mediated cyclisations have proved especially useful. The critical review illustrates the mechanistic considerations required for planning synthetic applications and a wide range of synthetic protocols and natural product syntheses are shown. The latest evidence for the mechanisms involved in aromatic homolytic substitution are presented. (152 references).

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Citations

Mar 12, 2011·Organic Letters·Gary A MolanderValerie A Braz
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