Synthetic strategies of supported atomic clusters for heterogeneous catalysis

Nature Communications
Hongpan RongYadong Li

Abstract

Supported atomic clusters with uniform metal sites and definite low-nuclearity are intermediate states between single-atom catalysts (SACs) and nanoparticles in size. Benefiting from the presence of metal-metal bonds, supported atomic clusters can trigger synergistic effects among every metal atom, which contributes to achieving unique catalytic properties different from SACs and nanoparticles. However, the scalable and precise synthesis and atomic-level insights into the structure-properties relationship of supported atomic clusters is a great challenge. This perspective presents the latest progress of the synthesis of supported atomic clusters, highlights how the structure affects catalytic properties, and discusses the limitations as well as prospects.

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Citations

Feb 20, 2021·Angewandte Chemie·Cheng TangShi-Zhang Qiao
Apr 6, 2021·Angewandte Chemie·Ningqiang ZhangYadong Li
Jul 23, 2021·Journal of the American Chemical Society·Tao DingTao Yao
Oct 5, 2021·Physical Chemistry Chemical Physics : PCCP·Alexander S Lisitsyn, Anastasiya S Kadtsyna
Oct 14, 2021·Chemical Reviews·Baljeet SinghRadek Zbořil

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Methods Mentioned

BETA
X-ray
chip
Infrared spectroscopy
transmission electron microscopy

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