Synthons for carbide complex chemistry

Chemical Communications : Chem Comm
Anders ReinholdtJesper Bendix

Abstract

The sterically accessible carbide complex, (Cy3P)Cl3Ru[triple bond, length as m-dash]C-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

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Citations

Jul 4, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Harrison J BarnettAnthony F Hill
Oct 17, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Anders ReinholdtRichard A Manzano
Jan 19, 2019·Chemical Communications : Chem Comm·Harrison J Barnett, Anthony F Hill
Jun 28, 2019·Chemical Communications : Chem Comm·Anders Reinholdt, Jesper Bendix
Oct 1, 2019·Chemical Communications : Chem Comm·Benjamin J Frogley, Anthony F Hill
Jan 30, 2020·Chemical Communications : Chem Comm·Anthony F Hill, Lachlan J Watson
Dec 19, 2019·Angewandte Chemie·Anthony Francis Hill, Harrison J Barnett
Apr 23, 2020·Chemical Communications : Chem Comm·Liam K BurtJörg Wagler
Jun 6, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Liam K Burt, Anthony F Hill
Jun 12, 2020·Chemical Communications : Chem Comm·Harrison J Barnett, Anthony F Hill
Sep 19, 2020·Chemical Communications : Chem Comm·Harrison J Barnett, Anthony F Hill
Jul 6, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Harrison J Barnett, Anthony F Hill
Aug 5, 2021·Chemical Communications : Chem Comm·Liam K Burt, Anthony F Hill
Mar 28, 2019·Inorganic Chemistry·Anders ReinholdtJesper Bendix
Nov 20, 2021·Chemical Reviews·Anders Reinholdt, Jesper Bendix

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Methods Mentioned

BETA
X-ray
NMR

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