Temperature-dependent schlieren effect in liquid flow for chemical analysis

Talanta
Jintana SuwanrutDuangjai Nacapricha

Abstract

In flow analysis, such as flow injection analysis, liquid lens is formed at the boundary between two adjacent liquid media which have different refractive indices. Light refraction at the liquid interface gives the so-called 'schlieren signal'. Schlieren effect is both concentration-dependent and temperature-dependent. In this work, the schlieren signal from temperature difference was quantitatively investigated for application in enthalpimetric measurement. The schlieren phenomena was then exploited for chemical analysis. A thermal insulated single flow line manifold was constructed using deionized water at 23 °C as the carrier. Deionized water at various temperatures in the range of 5-85 °C was injected into the carrier flow. A correlation between the schlieren signal and sample temperature was observed. A heat exchanger unit (HEU), consisting of a small volume glass-reaction chamber with a surrounding water jacket, was constructed. The unit was thermally insulated in a double layer cylindrical PVC unit. For demonstrating the applicability of temperature-dependent schlieren effect in chemical analysis, the exothermic oxidation reaction between acid dichromate and ethanol or ascorbic acid was employed with heat transferring to...Continue Reading

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.