Terminal alkyne insertion into a thiolate-bridged dirhodium hydride complex derived from heterolytic cleavage of H2

Chemical Communications : Chem Comm
Xiangyu ZhaoJingping Qu

Abstract

Thiolate-bridged dirhodium and diiridium complexes can facilely realize heterolytic cleavage of H2 across the metal-sulfur bond to generate the corresponding hydride bridged complexes. Furthermore, terminal alkynes can insert the Rh-H-Rh fragment to afford σ:π alkenyl bridged complexes and then convert to the corresponding alkenes in the presence of a reductant and an acid.

References

Sep 6, 2001·Journal of the American Chemical Society·R C LinckT B Rauchfuss
Sep 24, 2004·Journal of the American Chemical Society·Andrea IencoCarlo Mealli
Feb 20, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Shuang Liu, Guo-Xin Jin
Sep 14, 2007·Chemical Reviews·Juan C Fontecilla-CampsYvain Nicolet
Oct 27, 2007·Accounts of Chemical Research·Takao Ikariya, A John Blacker
Aug 8, 2008·Journal of the American Chemical Society·Yasuhiro OhkiKazuyuki Tatsumi
Mar 12, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Hidetake SeinoYasushi Mizobe
Jan 12, 2011·Journal of the American Chemical Society·Yanhui ChenJingping Qu
Mar 9, 2013·Angewandte Chemie·Baoguo ZhaoKuiling Ding
Jan 24, 2014·Angewandte Chemie·Lada ZámostnáBeatrice Braun
Jan 29, 2014·Chemical Reviews·Brian M HoffmanLance C Seefeldt
Mar 25, 2014·Chemical Reviews·Wolfgang LubitzEdward Reijerse
Sep 4, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Phillip S NejmanJ Derek Woollins
Nov 5, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng TongJingping Qu
Apr 14, 2017·Accounts of Chemical Research·Lukas OmannMartin Oestreich
May 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yahui ZhangJingping Qu
Aug 22, 2017·Chemical Communications : Chem Comm·Yixin ZhangJingping Qu
Nov 9, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yanpeng ZhangJingping Qu

❮ Previous
Next ❯

Citations

Jan 30, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Puhua SunJingping Qu
Aug 8, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jianzhe LiJingping Qu
Nov 27, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Sunlin XuJingping Qu

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.