The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

Dalton Transactions : an International Journal of Inorganic Chemistry
Thaige P GompaHenry S La Pierre

Abstract

The fundamental redox chemistry and valence electronic structure of the lanthanides in molecular complexes and extended solids continues to be a fertile area of research. The contemporary understanding of the accessible oxidation states of the lanthanide elements and the variability in their electronic structure is the result of several paradigm shifts. While the lanthanide elements have already found widespread use in technical and consumer applications, the continued reevaluation of basic redox properties is a central chemical concern to establish a more complete description of periodic properties. This fundamental understanding of valence electronic structure as it is derived from oxidation state and coordination environment is essential for the continued development of lanthanides in quantum information science and quantum materials research. This review presents the chemical and physical properties of tetravalent lanthanide ions in extended solids and molecules with a focus on the elements apart from cerium: praseodymium, neodymium, terbium, and dysprosium.

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Citations

Oct 21, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Luis M Aguirre QuintanaHenry S La Pierre
Sep 24, 2020·Chemistry : a European Journal·Moya A Hay, Colette Boskovic
Dec 20, 2020·Chemistry : a European Journal·Maxime TricoireGrégory Nocton
Feb 11, 2021·Chemistry : a European Journal·Dumitru-Claudiu SergentuJochen Autschbach
Jun 16, 2021·Chemical Communications : Chem Comm·Luis M Aguirre QuintanaHenry S La Pierre
Oct 9, 2020·Inorganic Chemistry·Roger KloditzJuliane März

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Methods Mentioned

BETA
ion exchange purification
X-ray
neutron diffraction
AFM
inelastic neutron scattering
inelastic neutron
optical spectroscopy

Software Mentioned

EasySpin

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