The dynamic crossover in water does not require bulk water

Physical Chemistry Chemical Physics : PCCP
David A TurtonKlaas Wynne

Abstract

Many of the anomalous properties of water may be explained by invoking a second critical point that terminates the coexistence line between the low- and high-density amorphous states in the liquid. Direct experimental evidence of this point, and the associated polyamorphic liquid-liquid transition, is elusive as it is necessary for liquid water to be cooled below its homogeneous-nucleation temperature. To avoid crystallization, water in the eutectic LiCl solution has been studied but then it is generally considered that "bulk" water cannot be present. However, recent computational and experimental studies observe cooperative hydration in which case it is possible that sufficient hydrogen-bonded water is present for the essential characteristics of water to be preserved. For femtosecond optical Kerr-effect and nuclear magnetic resonance measurements, we observe in each case a fractional Stokes-Einstein relation with evidence of the dynamic crossover appearing near 220 K and 250 K respectively. Spectra obtained in the glass state also confirm the complex nature of the hydrogen-bonding modes reported for neat room-temperature water and support predictions of anomalous diffusion due to "worm-hole" structure.

References

May 1, 1995·Physical Review. B, Condensed Matter·A P SokolovD Quitmann
Mar 19, 2004·Nature·Renato TorreRoberto Righini
Jul 23, 2004·The Journal of Chemical Physics·A BottiA K Soper
Jul 23, 2004·The Journal of Chemical Physics·Alberto De SantisDario Rocca
Nov 4, 2005·Proceedings of the National Academy of Sciences of the United States of America·Limei XuH E Stanley
Jun 6, 2006·Proceedings of the National Academy of Sciences of the United States of America·S-H ChenE Mamontov
Aug 16, 2006·Physical Review Letters·Jan SwensonRikard Bergman
Aug 22, 2006·Proceedings of the National Academy of Sciences of the United States of America·Sow-Hsin ChenLi Liu
Dec 13, 2006·Physical Review Letters·Pradeep KumarH E Stanley
Dec 29, 2006·Proceedings of the National Academy of Sciences of the United States of America·Francesco MallamaceSow-Hsin Chen
Jul 3, 2007·The Journal of Physical Chemistry. B·Wolfgang WachterGlenn Hefter
Mar 21, 2008·Physical Review Letters·Pradeep KumarH Eugene Stanley
Mar 21, 2008·Physical Review Letters·S PawlusA P Sokolov
May 2, 2008·The Journal of Chemical Physics·David A TurtonKlaas Wynne
May 31, 2008·The Journal of Physical Chemistry. B·Damien Laage, James T Hynes
Nov 13, 2008·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Song-Ho Chong
Jun 27, 2009·Proceedings of the National Academy of Sciences of the United States of America·D BanerjeeD Leporini
Sep 29, 2009·The Journal of Physical Chemistry. B·Eugene Mamontov
Dec 2, 2009·The Journal of Chemical Physics·David A Turton, Klaas Wynne
Jan 12, 2010·The Journal of Physical Chemistry. B·Francesco MallamaceSow-Hsin Chen
Mar 17, 2010·Proceedings of the Japan Academy. Series B, Physical and Biological Sciences·Osamu Mishima
Apr 7, 2010·Physical Review Letters·W DosterH Scheer
Apr 10, 2010·Physical Chemistry Chemical Physics : PCCP·David A TurtonKlaas Wynne
May 22, 2010·Science·K J TielrooijH J Bakker
Dec 21, 2010·The Journal of Physical Chemistry. a·Ly Le, Valeria Molinero
Mar 15, 2011·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Pál JedlovszkyRenzo Vallauri
Dec 3, 2011·Proceedings of the National Academy of Sciences of the United States of America·Marco G MazzaGiancarlo Franzese
Jul 1, 2008·Journal of Chemical Theory and Computation·L PetitC Adamo

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Citations

Dec 3, 2013·The Journal of Chemical Physics·P GalloM Rovere
Feb 12, 2014·The Journal of Chemical Physics·Ruiting Zhang, Wei Zhuang
Mar 5, 2016·Chemical Reviews·Silvina CervenyLimei Xu
Nov 2, 2015·The Review of Scientific Instruments·K PolokB Ratajska-Gadomska
Jan 13, 2015·Physical Chemistry Chemical Physics : PCCP·E MamontovM Ohl
Jun 15, 2017·The Journal of Physical Chemistry Letters·Gopakumar RamakrishnanKlaas Wynne
Jun 4, 2014·Nature Communications·David A TurtonKlaas Wynne
Jun 24, 2019·The Journal of Chemical Physics·Philipp MünznerCatalin Gainaru
Jan 3, 2020·Physical Chemistry Chemical Physics : PCCP·S A M Shamimul AhsanYashonath Subramanian
May 22, 2013·Physical Chemistry Chemical Physics : PCCP·E Mamontov, M Ohl
Sep 27, 2019·Physical Chemistry Chemical Physics : PCCP·Johannes BachlerThomas Loerting
Aug 12, 2015·The Journal of Physical Chemistry Letters·Joanna MossesKlaas Wynne
Aug 28, 2014·The Journal of Physical Chemistry. B·T C ChanK S Chan
Oct 26, 2018·Journal of the American Chemical Society·Joonhyung LimMinhaeng Cho

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