The formation, reactivity and interconversion of novel small eta(1)- and eta(3)-triazacyclononane complexes of rhodium(I) and rhodium(III)

Dalton Transactions : an International Journal of Inorganic Chemistry
Andrew L GottClaire N Temple

Abstract

We have successfully synthesised and characterised a number of eta(1)- and eta(3)-triazacyclononane Rh(I) and Rh(III) derivatives. By using different reaction conditions, we have been able to convert one of the eta(1)-triazacyclononane complexes to an eta(3)-derivative. Also, we have observed a rare example of an addition of an organic fragment to a metal bound ligand to form a quaternary carbon centre.

References

Aug 23, 2001·Journal of the American Chemical Society·J A Schmidt, J Arnold

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Citations

Jul 11, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Andrew L GottThomas J Podesta

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