The in situ technique of aqueous binding concentration and diffusion for measurements of arsenate concentrations in lake waters

Analytica Chimica Acta
Weijia Li, Dengpan Qin

Abstract

Arsenic contaminations in waters are concerned worldwide. This research was to examine an in situ method of aqueous binding concentration and diffusion (ABCD) technique with an aqueous solution of metal immobilized polycationic polymer (MIP) as a binding phase and a dialysis membrane as a diffusive layer to pre-concentrate trace arsenate in lake waters. Although the maximum binding capacity of arsenate to MIP was influenced by the presence of anions in water, the binding phase was capable of pre-concentrating arsenate in lake water. This in situ pre-concentration technique was combined with light emitting diodes (LED) for semi-on line detection of trace arsenate in waters. The system was eventually validated in lake waters in lab and in natural lake waters in China. In this work, new colorimetric method for detection of arsenate in the binding phase has been developed to minimize the potential spectra interferences of silicates, phosphates and other oxyanions. Potassium iodide was used to reduce arsenate to arsenite before the solution was mixed with the colour generation reagent of RhodamineB.

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.