The Influence of Chemical Modification on Linker Rotational Dynamics in Metal-Organic Frameworks

Angewandte Chemie
Joshua T DamronAyyalusamy Ramamoorthy

Abstract

The robust synthetic flexibility of metal-organic frameworks (MOFs) offers a promising class of tailorable materials, for which the ability to tune specific physicochemical properties is highly desired. This is achievable only through a thorough description of the consequences for chemical manipulations both in structure and dynamics. Magic angle spinning solid-state NMR spectroscopy offers many modalities in this pursuit, particularly for dynamic studies. Herein, we employ a separated-local-field NMR approach to show how specific intraframework chemical modifications to MOF UiO-66 heavily modulate the dynamic evolution of the organic ring moiety over several orders of magnitude.

References

Jun 13, 2003·Nature·Omar M YaghiJaheon Kim
Jul 13, 2004·Angewandte Chemie·Mario RubenJean-Marie Lehn
Oct 3, 2006·Angewandte Chemie·Satoshi HorikeSusumu Kitagawa
Jan 17, 2008·Chemical Society Reviews·Gérard Férey
Feb 22, 2008·Journal of the American Chemical Society·Stephanie L GouldMiguel A Garcia-Garibay
Mar 19, 2008·The Journal of Chemical Physics·Eduardo Ribeiro deAzevedoDetlef Reichert
Sep 27, 2008·Journal of the American Chemical Society·Jasmina Hafizovic CavkaKarl Petter Lillerud
Apr 23, 2009·Chemical Society Reviews·Gérard Férey, Christian Serre
Jun 1, 2010·Angewandte Chemie·Daniil I KolokolovGérard Férey
Dec 3, 2010·Nature Chemistry·Satoshi HorikeSusumu Kitagawa
Sep 29, 2011·Journal of the American Chemical Society·Patricia HorcajadaChristian Serre
Mar 1, 2012·Journal of the American Chemical Society·J Alberto Rodríguez-VelamazánSusumu Kitagawa
May 31, 2012·Proceedings of the National Academy of Sciences of the United States of America·Wataru Setaka, Kentaro Yamaguchi
Jul 6, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuting HuangYingwei Li
Nov 8, 2012·Solid State Nuclear Magnetic Resonance·Andre Sutrisno, Yining Huang
Mar 13, 2014·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Andreas SchneemannRoland A Fischer
May 31, 2014·Chemical Society Reviews·A SchneemannR A Fischer
Mar 25, 2015·Nature Chemistry·Alok S TayiSamuel I Stupp
May 30, 2015·Science·Anna G Slater, Andrew I Cooper
Aug 14, 2015·Advanced Materials·Ze ChangXian-He Bu
Sep 15, 2015·Journal of the American Chemical Society·Munehiro InukaiSusumu Kitagawa
Mar 11, 2017·Proceedings of the National Academy of Sciences of the United States of America·Florian MoreauMartin Schröder

❮ Previous
Next ❯

Citations

Mar 20, 2019·Nature Nanotechnology·Wojciech DanowskiBen L Feringa
Dec 6, 2019·Chemistry : a European Journal·Elena Kolodzeiski, Saeed Amirjalayer
May 5, 2020·Chemical Communications : Chem Comm·Jing ChenDavid J Young
Sep 10, 2020·Advanced Materials·Shenhui LiFeng Deng
Mar 6, 2019·Nanomaterials·Adrian Gonzalez-NelsonMonique A van der Veen
Mar 9, 2021·Angewandte Chemie·Jinqiao DongDan Zhao
Jul 30, 2021·Journal of the American Chemical Society·Adrian Gonzalez-NelsonMonique A van der Veen
Apr 23, 2019·ACS Applied Materials & Interfaces·Ghada AyoubOmar K Farha
Sep 25, 2018·Langmuir : the ACS Journal of Surfaces and Colloids·Tobias W KemnitzerJürgen Senker

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.