The molecular recognition controlled stereomutation cycle in a dynamic helical assembly

Organic & Biomolecular Chemistry
Mohit KumarSubi J George

Abstract

Perylene bisimide functionalized with a phosphate recognition unit assembles into a left-handed, right-handed or racemic helical assembly on binding with AMP, ATP and inorganic phosphates, respectively. Thus, competitive binding among these multivalent guests was utilized for completing an unprecedented helix mutation cycle in a dynamic supramolecular assembly.

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Citations

Feb 23, 2018·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Israel Carreira-BarralDavid Esteban-Gómez
Jun 11, 2020·Angewandte Chemie·Ananya MishraSubi J George
Sep 12, 2017·Journal of the American Chemical Society·Chidambar KulkarniSubi J George
Aug 29, 2017·Journal of the American Chemical Society·Shikha DhimanSubi J George

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