PMID: 11322540Apr 27, 2001Paper

The persistent radical effect in organic synthesis

Chemistry : a European Journal
Armido Studer

Abstract

The persistent radical effect (PRE) is a principle that explains the highly selective cross-coupling between a persistent and a transient radical when both species are formed at equal rates. In this paper, the concept of the PRE is briefly discussed. Applications of the PRE in different reactions such as Co-mediated radical addition and cyclization reactions, Kharasch reactions catalyzed by transition metals, the Barton reaction, and our nitroxide-mediated tin-free radical cyclizations are presented. Some future perspectives for the PRE in organic synthesis are also provided.

References

Oct 25, 2001·The Journal of Organic Chemistry·Andrew J. ClarkMark E. Smith
Aug 3, 1945·Science·M S KharaschW H Urry

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Citations

Apr 17, 2014·Chemistry : a European Journal·Stephanie KindtMarkus R Heinrich
Sep 21, 2011·Chemistry : a European Journal·Chang-Liang SunZhang-Jie Shi
Aug 27, 2014·Angewandte Chemie·Stefanie K FehlerMarkus R Heinrich
Jun 9, 2016·Angewandte Chemie·Stephanie KindtMarkus R Heinrich
Dec 23, 2011·The Journal of Organic Chemistry·Hannelore JaschMarkus R Heinrich
Mar 18, 2017·The Journal of Organic Chemistry·Samir Z Zard
Jun 22, 2017·Accounts of Chemical Research·Xi Wang, Armido Studer
Jun 23, 2006·Chemistry : a European Journal·Béatrice Quiclet-Sire, Samir Z Zard
Aug 24, 2007·Chemical Communications : Chem Comm·Taramatee RamnialCharles J Walsby
Jul 1, 2009·Macromolecular Rapid Communications·Marion K Brinks, Armido Studer
Aug 15, 2012·Angewandte Chemie·Armido Studer
May 10, 2017·Proceedings. Mathematical, Physical, and Engineering Sciences·Béatrice Quiclet-Sire, Samir Z Zard
May 11, 2018·Topics in Current Chemistry·Richard S Glass
Oct 20, 2018·Angewandte Chemie·Luca BuzzettiPaolo Melchiorre
Apr 27, 2019·Chemistry : a European Journal·Qiang WangQingmin Wang
Jul 9, 2009·Angewandte Chemie·Martin PouliotThomas Vogler
Sep 29, 2011·Chemical Communications : Chem Comm·Guo-Ping YongYing-Zhou Li
Feb 19, 2011·Chemical Communications : Chem Comm·Maike BeckerArmido Studer
Apr 27, 2011·Angewandte Chemie·Tynchtyk Amatov, Ullrich Jahn
Jul 5, 2012·Chemical Communications : Chem Comm·Hailong YangJincheng Mao
Apr 24, 2012·Chemical Communications : Chem Comm·Patrizia Gentili, Silvia Pedetti
Feb 27, 2015·Chemical Communications : Chem Comm·Yi LiArmido Studer
Oct 16, 2015·Angewandte Chemie·Armido Studer, Dennis P Curran
Aug 22, 2014·Nature Chemistry·Armido Studer, Dennis P Curran
Nov 8, 2018·Chemistry : a European Journal·Heng Jiang, Armido Studer
Jun 30, 2018·Chemical Communications : Chem Comm·Bo ZhuZhong-Min Su

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