The photochemical release of dissolved organic matter from resuspended sediments: Insights from fluorescence spectroscopy

Chemosphere
Bin HuYue Shi

Abstract

Sediments exposed to sunlight can serve as an important source of dissolved organic carbon (DOC) and nutrients to overlying waters. However, the photochemical release processes of dissolved organic matter (DOM) from resuspended sediments and the characteristics of photoreleased DOM are not fully understood. In this study, excitation-emission matrix fluorescence combined with parallel factor analysis (EEMs-PARAFAC) was used to study the photochemical release of DOM qualitatively and quantitatively. The EEMs-PARAFAC demonstrated that the photoreleased DOM is dominated by humic-like substances, and the photorelease process could be consist of the photoproduction and photodegradation of DOM. The concurrent photodegradation may result in the underestimation of photoreleased DOM. Moreover, the significant increases in DOC content and fluorescence intensity of humic-like components along with increasing nitrate and ferric ion indicated that nitrate and ferric ion could facilitate the photoproduction of DOM through the photochemical produced hydroxyl radical. However, the decreases in DOC and fluorescence intensity were also observed at high concentration of nitrate and ferric ion, owing to the photodegradation of DOM by redundant hydr...Continue Reading

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