The Polyoxovanadate-Based Carboxylate Derivative K6 H[VV17 VIV12 (OH)4 O60 (OOC(CH2 )4 COO)8 ]·nH2 O: Synthesis, Crystal Structure, and Catalysis for Oxidation of Sulfides

Inorganic Chemistry
Ke WangJingyang Niu

Abstract

The high-nuclearity polyoxovanadate-based carboxylate derivative K6H[VV17VIV12(OH)4O60(OOC(CH2)4COO)8]·nH2O (1) has been successfully synthesized by conventional aqueous methods and structurally characterized. The [VV17VIV12(OH)4O60(OOC(CH2)4COO)8]7- polyanion is built up from three cages: one {VV17(OH)4O44} cage and two identical [(VIV3O6)2(OOC(CH2)4COO)4]8- cages. Of the three cages, the {VV17(OH)4O44} is a purely inorganic polyoxovanadate cluster, whereas each of the [(VIV3O6)2(OOC(CH2)4COO)4]8- cages is a vanadium-based organic-inorganic hybrid cluster framed via four adipate ligands linking simultaneously to two triangular {V3} units. The two [(VIV3O6)2(OOC(CH2)4COO)4]8- cages are covalently attached to the central {VV17(OH)4O44} cage via V-O-V bonds in a linear arrangement, resulting in a {V29}-based hybrid cluster skeleton. The catalytic properties of compound 1 for the oxidation of sulfides by tert-butyl hydroperoxide were investigated, and the result indicates that 1 exhibits excellent catalytic activity for the oxidation of sulfides under mild conditions.

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Citations

Jan 28, 2020·Chemistry : a European Journal·Jing Yang NiuJingping Wang
Jul 30, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Xianqiang HuangJikun Li

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