Abstract
Experiments using pulsed Fourier-transform microwave spectroscopy have been performed to probe the reaction between the methyl substituted Criegee intermediate, CH3CHOO, and hydrogen chloride. Two conformers of the product derived from the insertion of HCl within CH3CHOO, chloroethyl hydroperoxide, formed in the discharged plasma of a CH3CHI2/O2/HCl gas mixture, were identified through their experimentally determined rotational and quadrupole coupling constants. The relative abundance of the detected species indicates that the reaction of the anti-CH3CHOO conformer is faster than that of the syn-CH3CHOO conformer. The results presented in this work constitute the first experimental information about the reaction between CH3CHOO and HCl.
References
Aug 20, 2005·The Journal of Chemical Physics·Yoshihiro SumiyoshiYasuki Endo
Mar 26, 2008·Chemical Society Reviews·David Johnson, George Marston
Jun 21, 2011·Physical Chemistry Chemical Physics : PCCP·J M AngladaM Torrent-Sucarrat
Jan 17, 2012·Science·Oliver WelzCraig A Taatjes
Apr 13, 2013·Science·Craig A TaatjesCarl J Percival
Oct 12, 2013·Physical Chemistry Chemical Physics : PCCP·Daniel StonePaul Seakins
Jan 15, 2014·The Journal of Chemical Physics·Masakazu Nakajima, Yasuki Endo
Mar 29, 2014·Angewandte Chemie·Oliver WelzCraig A Taatjes
Apr 10, 2014·The Journal of Chemical Physics·Masakazu Nakajima, Yasuki Endo
Sep 15, 2014·The Journal of Chemical Physics·Wei-Lun TingJim Jr-Min Lin
Sep 27, 2014·Science·Fang LiuMarsha I Lester
Jan 9, 2015·Science·Wen ChaoJim Jr-Min Lin
Apr 23, 2015·Physical Chemistry Chemical Physics : PCCP·Yue ZhaoBarbara J Finlayson-Pitts
May 12, 2015·Nature Communications·Hui-Yu LinYuan-Pern Lee
Nov 2, 2015·The Journal of Chemical Physics·Masakazu Nakajima, Yasuki Endo
Feb 16, 2016·The Journal of Chemical Physics·Yi FangMarsha I Lester
Mar 30, 2016·Physical Chemistry Chemical Physics : PCCP·Tran B NguyenPaul O Wennberg
Jul 22, 2016·Angewandte Chemie·Elizabeth S ForemanCraig Murray
Nov 17, 2016·The Journal of Chemical Physics·Carlos CabezasYasuki Endo
Apr 28, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Carlos Cabezas, Yasuki Endo
Aug 15, 2017·Physical Chemistry Chemical Physics : PCCP·Leonid ShepsCarl J Percival
Jan 8, 2018·The Journal of Chemical Physics·Carlos Cabezas, Yasuki Endo