The reactivity of cyclo-(P5tBu4)- towards group 13, 14 and 15 metal chlorides: complexation and formation of cyclooligophosphanes, [cyclo-(P5tBu4)]2 and [cyclo-(P4tBu3)PtBu]2, by reductive elimination

Dalton Transactions : an International Journal of Inorganic Chemistry
Andrea SchislerEvamarie Hey-Hawkins

Abstract

[Na(THF)4][cyclo-(P5tBu4)] (1) reacts with Et2AlCl and GeCl4 to give Et2Al[cyclo-(P5tBu4)](THF) (2) and, in low yield, GeCl3[cyclo-(P5tBu4)], respectively, while the reaction of 1 with SnCl2, PbCl2 or BiCl3 results in the formation of the structural isomers [cyclo-(P5tBu4)]2 (3) and [cyclo-(P4tBu3)PtBu]2 (4)(besides other cyclic phosphanes) and elemental metal.

References

Jan 1, 1995·Acta Crystallographica. Section A, Foundations of Crystallography·R H Blessing

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Citations

Jul 20, 2007·Chemistry : a European Journal·Santiago Gómez-RuizEvamarie Hey-Hawkins
Dec 7, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Gómez-Ruiz, Evamarie Hey-Hawkins
Apr 3, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Gómez-RuizEvamarie Hey-Hawkins
Apr 3, 2008·Chemistry : a European Journal·Santiago Gómez-RuizEvamarie Hey-Hawkins
Apr 9, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Gómez-RuizEvamarie Hey-Hawkins
Sep 8, 2005·Angewandte Chemie·Robert Wolf, Evamarie Hey-Hawkins
Oct 2, 2019·Angewandte Chemie·Martin PieschManfred Scheer
Jan 27, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Robert WolfEvamarie Hey-Hawkins
Oct 21, 2016·Chemistry : a European Journal·Anup K AdhikariEvamarie Hey-Hawkins
Mar 19, 2008·Inorganic Chemistry·Eamonn ConradMichael J Ferguson
Sep 18, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Volker Jens EilrichEvamarie Hey-Hawkins

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