The synthesis and efficient one-pot catalytic "self-breeding" of asymmetrical NC(sp(3))E-hybridised pincer complexes

Chemical Communications : Chem Comm
Xiang-Yuan YangPak-Hing Leung

Abstract

Cyclopalladation of the pyridyl-substituted chiral phosphine sulfide (N-P=S) and oxide (N-P=O) compounds afforded the asymmetric N-C(sp(3))*-S and N-C(sp(3))*-O pincer complexes. When applied as catalysts in asymmetric hydrophosphination, the newly developed aliphatic pincer catalyst could be recycled over three runs and obtained in large quantities via a one-pot "self-breeding" catalytic protocol.

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Aug 26, 2014·Chemistry : a European Journal·Jingjun HaoDavit Zargarian
Nov 22, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiang-Yuan YangPak-Hing Leung
Jun 30, 2015·Angewandte Chemie·Klara J JonassonOla F Wendt

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Citations

Jan 11, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Xi-Rui LiPak-Hing Leung
Jul 20, 2018·Chemistry, an Asian Journal·Abdul SadeerPak-Hing Leung
Dec 21, 2018·Chemical Communications : Chem Comm·Félix LeónAntonio Pizzano
May 16, 2019·Organic & Biomolecular Chemistry·Jin-Kui LiuMao-Ping Song
Jul 12, 2019·Chemistry : a European Journal·Wee Shan TayPak-Hing Leung
Mar 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Wee Shan TayPak-Hing Leung

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