The trigonal prism in coordination chemistry

Chemistry : a European Journal
Eduard CremadesSantiago Alvarez

Abstract

Herein we analyze the accessibility of the trigonal-prismatic geometry to metal complexes with different electron configurations, as well as the ability of several hexadentate ligands to favor that coordination polyhedron. Our study combines i) a structural database analysis of the occurrence of the prismatic geometry throughout the transition-metal series, ii) a qualitative molecular orbital analysis of the distortions expected for a trigonal-prismatic geometry, and iii) a computational study of complexes of several transition-metal ions with different hexadentate ligands. Also the tendency of specific electron configurations to present a cis bond-stretch Jahn-Teller distortion is analyzed.

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Citations

Jul 12, 2016·Chemical Reviews·Roald HoffmannGabriele Manca
Nov 17, 2015·Chemical Communications : Chem Comm·Elizabeth A PedrickTrevor W Hayton
Sep 14, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Luis D Rosales-VázquezAntonio Téllez-López
Jun 7, 2018·Angewandte Chemie·Javier Castells-GilCarlos Martí-Gastaldo
Jul 12, 2012·Chemistry : a European Journal·Inbal Tuvi-Arad, David Avnir
Jul 20, 2018·Chemistry : a European Journal·Abel CarrerasPere Alemany
Jun 12, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Simon N ChildJohn Fielden
Feb 26, 2013·Journal of Computational Chemistry·David CasanovaSantiago Alvarez
Mar 21, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Jordi Cirera, Santiago Alvarez
Mar 5, 2011·Chemistry : a European Journal·Said El-Kurdi, Konrad Seppelt
May 16, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul KelleyTheodor Agapie
Jul 29, 2020·Chemistry : a European Journal·Víctor OestreicherMatías Jobbágy
May 11, 2021·Advanced Materials·Nanzhong WuYongbing Tang
Feb 6, 2014·The Journal of Physical Chemistry Letters·Valentin V NovikovYan Z Voloshin
Jun 22, 2012·Inorganic Chemistry·Lani A SeamanTrevor W Hayton
Mar 17, 2020·Journal of the American Chemical Society·Natalia M PadialCarlos Marti-Gastaldo
Nov 28, 2019·Inorganic Chemistry·Natalija Pantalon JurajSrećko I Kirin
Sep 9, 2021·Inorganic Chemistry·Sergey V OvsyannikovLeonid Dubrovinsky
Sep 30, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Hyuk-Yong KwonElena Jakubikova

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